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Solution processed La0.8Sr0.2MnO3–Bi1.44Y0.56O3 composite thin films with self-assembled nanolayered structures

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Abstract

To lower solid oxide fuel cell operating temperatures down to ≤ 700°C, we fabricated La0.8Sr0.2MnO3–Bi1.44Y0.56O3 (LSM-YDB) cathode films from a “single-pot” mixture of polymeric LSM and YDB precursors, which yielded nanocomposite-structured films with long triple phase boundary lengths. Alternating nanolayers of LSM and YDB phases were revealed by STEM-EDS analysis. The microstructure forming at 600°C contained YDB nanoparticles in the LSM phase and LSM nanoparticles in the YDB phase, ensuring 3-D interconnectivity for each phase and a percolation pathway. An area specific polarization resistance of 0.55 cm2 was measured at 600°C.

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Acknowledgments

This work was funded by the Scientific and Technological Research Council of Turkey (TUBITAK) under the grant number 217M031.

Funding

Türkiye Bilimsel ve Teknolojik Araştırma Kurumu, 217M031, Aligul Buyukaksoy

Author information

Authors and Affiliations

  1. Department of Physics 41400, Gebze Technical University, Kocaeli, Turkey

    Busra Aktas

  2. Department of Materials Science and Engineering, Gebze Technical University, 41400, Kocaeli, Turkey

    Batuhan Bal, M. Unsal Unver & Aligul Buyukaksoy

  3. The School of Chemical Engineering, Oklahoma State University, Stillwater, OK, 74078, USA

    Batuhan Bal

  4. Nanotechnology Research and Application Center, Sabancı University, SUNUM, 34956, Istanbul, Turkey

    Meltem Sezen & Cleva W. Ow-Yang

  5. Faculty of Engineering and Natural Sciences, Sabancı University, 34956, Istanbul, Turkey

    Cleva W. Ow-Yang

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  1. Busra Aktas
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  2. Batuhan Bal
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  3. Meltem Sezen
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  4. Cleva W. Ow-Yang
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  5. M. Unsal Unver
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  6. Aligul Buyukaksoy
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Correspondence to Aligul Buyukaksoy.

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Aktas, B., Bal, B., Sezen, M. et al. Solution processed La0.8Sr0.2MnO3–Bi1.44Y0.56O3 composite thin films with self-assembled nanolayered structures. MRS Communications 13, 1357–1362 (2023). https://doi.org/10.1557/s43579-023-00461-z

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