Abstract
Carrier transport mechanism in Si-doped n-type α-Ga2O3 thin film on m-plane sapphire substrate was investigated by temperature-dependent Hall effect measurements (30–300 K). All films show dislocation density of about ~ 1010–1011 cm−2. In non-degenerate α-Ga2O3, an impurity-band effect is obvious in the low temperature region, and dislocation scattering is the dominant scattering mechanism. In contrast, in degenerate α-Ga2O3, although the dislocation density is comparable to the non-degenerate one, the mobility is dominated by ionized impurity scattering, due to the heavy screening of charged dislocations. The analysis indicates that the carrier transport mechanism in α-Ga2O3 with high dislocation density is different from each other depending on whether α-Ga2O3 is degenerate or non-degenerate. Finally, we estimate critical dislocation density for dislocation-insensitive mobility in α-Ga2O3 on sapphire substrate, and indicate that dislocation densities below ~ 1 × 107–1 × 108 cm−2 will be required for lightly doped drift layers in devices.
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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
S.J. Pearton, J. Yang, P.H. Cary, F. Ren, J. Kim, M.J. Tadjer, M.A. Mastro, Appl. Phys. Rev. 5, 011301 (2018)
E. Ahmadi, Y. Oshima, J. Appl. Phys. 126, 160901 (2019)
Y. Guo, J. Zhang, F. Zhu, Z.X. Yang, J. Xu, J. Yu, J. Phys. D. Appl. Phys. 54, 243001 (2021)
A.J. Green, J. Speck, G. **ng, P. Moens, F. Allerstam, K. Gumaelius, T. Neyer, A. Arias-Purdue, V. Mehrotra, A. Kuramata, K. Sasaki, S. Watanabe, K. Koshi, J. Blevins, O. Bierwagen, S. Krishnamoorthy, K. Leedy, A.R. Arehart, A.T. Neal, S. Mou, S.A. Ringel, A. Kumar, A. Sharma, K. Ghosh, U. Singisetti, W. Li, K. Chabak, K. Liddy, A. Islam, S. Rajan, S. Graham, S. Choi, Z. Cheng, M. Higashiwaki, APL Mater. 10, 029201 (2022)
D. Shinohara, S. Fujita, Jpn. J. Appl. Phys. 47, 7311 (2008)
A. Segura, L. Artús, R. Cuscó, R. Goldhahn, M. Feneberg, Phys. Rev. Mater. 1, 024604 (2017)
G.T. Dang, T. Kawaharamura, M. Furuta, M.W. Allen, IEEE Trans. Electron. Devices 62, 3640 (2015)
M. Oda, R. Tokuda, H. Kambara, T. Tanikawa, T. Sasaki, T. Hitora, Appl. Phys. Express 9, 021101 (2016)
Y.J. Jeong, J.-H. Park, M.J. Yeom, I. Kang, J.Y. Yang, H. Kim, D.-W. Jeon, G. Yoo, Appl. Phys. Express 15, 074001 (2022)
T. Shinohe, in 2022 Int. Power Electron. Conf. (IPEC-Himeji 2022- ECCE Asia) (IEEJ-IAS, 2022), pp. 627–631
S. Kan, S. Takemoto, K. Kaneko, I. Takahashi, M. Sugimoto, T. Shinohe, S. Fujita, Appl. Phys. Lett. 113, 212104 (2018)
K. Kaneko, Y. Masuda, S.I. Kan, I. Takahashi, Y. Kato, T. Shinohe, S. Fujita, Appl. Phys. Lett. 118, 102104 (2021)
J.G. Hao, H.H. Gong, X.H. Chen, Y. Xu, F.-F. Ren, S.L. Gu, R. Zhang, Y.D. Zheng, J.D. Ye, Appl. Phys. Lett. 118, 261601 (2021)
N. Suzuki, K. Kaneko, S. Fujita, J. Cryst. Growth 401, 670 (2014)
R.H. French, J. Am. Ceram. Soc. 73, 477 (1990)
K. Kaneko, H. Kawanowa, H. Ito, S. Fujita, Jpn. J. Appl. Phys. 51, 020201 (2012)
R. **no, C.S. Chang, T. Onuma, Y. Cho, S.-T. Ho, D. Rowe, M.C. Cao, K. Lee, V. Protasenko, D.G. Schlom, D.A. Muller, H.G. **ng, D. Jena, Sci. Adv. 7, eabd5891 (2021)
T. Maeda, M. Okigawa, Y. Kato, I. Takahashi, T. Shinohe, AIP Adv. 10, 125119 (2020)
K. Akaiwa, K. Kaneko, K. Ichino, S. Fujita, Jpn. J. Appl. Phys. 55, 1202BA (2016)
K. Akaiwa, K. Ota, T. Sekiyama, T. Abe, T. Shinohe, K. Ichino, Phys. Status Solidi A 217, 1900632 (2020)
R.J. Molnar, T. Lei, T.D. Moustakas, Appl. Phys. Lett. 62, 72 (1993)
D.C. Look, J.R. Sizelove, Phys. Rev. Lett. 82, 1237 (1999)
C. Mavroidis, J.J. Harris, M.J. Kappers, C.J. Humphreys, Z. Bougrioua, J. Appl. Phys. 93, 9095 (2003)
P. Pampili, D.V. Dinh, V.Z. Zubialevich, P.J. Parbrook, J. Phys. D: Appl. Phys. 51, 06LT01 (2018)
S.M. Sze, Physics of Semiconductor Devices, 2nd edn. (Wiley, Hoboken, 1981)
M. Marezio, J.P. Remeika, J. Chem. Phys. 46, 1862 (1967)
D. Cherns, C.G. Jiao, Phys. Rev. Lett. 87, 205504 (2001)
M. Lundstrom, Fundamentals of Carrier Transport, 2nd edn. (Cambridge University Press, Cambridge, 2000)
B. Pödör, Phys. Status Solidi B 16, K167 (1966)
N.G. Weimann, L.F. Eastman, D. Doppalapudi, H.M. Ng, T.D. Moustakas, J. Appl. Phys. 83, 3656 (1998)
E. Chikoidze, H.J. Von Bardeleben, K. Akaiwa, E. Shigematsu, K. Kaneko, S. Fujita, Y. Dumont, J. Appl. Phys. 120, 025109 (2016)
T.C. Ma, X.H. Chen, Y. Kuang, L. Li, J. Li, F. Kremer, F.F. Ren, S.L. Gu, R. Zhang, Y.D. Zheng, H.H. Tan, C. Jagadish, J.D. Ye, Appl. Phys. Lett. 115, 182101 (2019)
N.F. Mott, Rev. Mod. Phys. 40, 677 (1968)
Y.P. Song, H.Z. Zhang, C. Lin, Y.W. Zhu, G.H. Li, F.H. Yang, D.P. Yu, Phys. Rev. B 69, 075304 (2004)
P.P. Edwards, M.J. Sienko, Phys. Rev. B 17, 2575 (1978)
H.M. Ng, D. Doppalapudi, T.D. Moustakas, N.G. Weimann, L.F. Eastman, Appl. Phys. Lett. 73, 821 (1998)
C.T. Walker, R.O. Pohl, Phys. Rev. 131, 1433 (1962)
S.K. Estreicher, T.M. Gibbons, B. Kang, M.B. Bebek, J. Appl. Phys. 115, 012012 (2014)
S.K. Estreicher, T.M. Gibbons, M.B. Bebek, J. Appl. Phys. 117, 112801 (2015)
T. Wang, J. Carrete, N. Mingo, G.K.H. Madsen, ACS Appl. Mater. Interfaces 11, 8175 (2019)
A. Sharma, U. Singisetti, Appl. Phys. Lett. 118, 032101 (2021)
Y.J. Zhang, Z.P. Wang, Y. Kuang, H.H. Gong, J.G. Hao, X.Y. Sun, F.-F. Ren, Y. Yang, S.L. Gu, Y.D. Zheng, R. Zhang, J.D. Ye, Appl. Phys. Lett. 120, 121601 (2022)
B. Pödör, Phys. Status Solidi A 2, K197 (1970)
Z. Guo, A. Verma, X. Wu, F. Sun, A. Hickman, T. Masui, A. Kuramata, M. Higashiwaki, D. Jena, T. Luo, Appl. Phys. Lett. 106, 111909 (2015)
M. Stokey, R. Korlacki, M. Hilfiker, H.G. **ng, D. Jena, M. Schubert, Phys. Rev. Mater. 6, 014601 (2022)
M. Feneberg, J. Nixdorf, M.D. Neumann, N. Esser, L. Artús, R. Cuscó, T. Yamaguchi, R. Goldhahn, Phys. Rev. Mater. 2, 044601 (2018)
M. Hilfiker, U. Kilic, M. Stokey, R. **no, Y. Cho, H.G. **ng, D. Jena, R. Korlacki, M. Schubert, Appl. Phys. Lett. 119, 092103 (2021)
H. He, R. Orlando, M.A. Blanco, R. Pandey, E. Amzallag, I. Baraille, M. Rérat, Phys. Rev. B 74, 195123 (2006)
R.K. Ham, Philos. Mag. 6, 1183 (1961)
D. Kapolnek, X.H. Wu, B. Heying, S. Keller, B.P. Keller, U.K. Mishra, S.P. Denbaars, J.S. Speck, Appl. Phys. Lett. 67, 1541 (1995)
D.C. Look, C.E. Stutz, R.J. Molnar, K. Saarinen, Z. Liliental-Weber, Solid State Commun. 117, 571 (2001)
D.C. Look, K.D. Leedy, L. Vines, B.G. Svensson, A. Zubiaga, F. Tuomisto, D.R. Doutt, L.J. Brillson, Phys. Rev. B 84, 115202 (2011)
D.C. Look, K.D. Leedy, Sci. Rep. 9, 1290 (2019)
K. Ueno, T. Fudetani, Y. Arakawa, A. Kobayashi, J. Ohta, H. Fujioka, APL Mater. 5, 126102 (2017)
B. Gunning, J. Lowder, M. Moseley, W. Alan Doolittle, Appl. Phys. Lett. 101, 082106 (2012)
N. Miller, E.E. Haller, G. Koblmüller, C. Gallinat, J.S. Speck, W.J. Schaff, M.E. Hawkridge, K.M. Yu, J.W. Ager, Phys. Rev. B 84, 075315 (2011)
N. Ma, N. Tanen, A. Verma, Z. Guo, T. Luo, H.G. **ng, D. Jena, Appl. Phys. Lett. 109, 212101 (2016)
R. **no, N. Yoshimura, K. Kaneko, S. Fujita, Jpn. J. Appl. Phys. 58, 120912 (2019)
Y. Oshima, K. Kawara, T. Shinohe, T. Hitora, M. Kasu, S. Fujita, APL Mater. 7, 022503 (2019)
R. **no, T. Uchida, K. Kaneko, S. Fujita, Appl. Phys. Express 9, 071101 (2016)
M. Oda, K. Kaneko, S. Fujita, T. Hitora, Jpn. J. Appl. Phys. 55, 1202B4 (2016)
H. Takane, K. Kaneko, Y. Ota, S. Fujita, Jpn. J. Appl. Phys. 60, 055501 (2021)
M. Grundmann, Appl. Phys. Lett. 116, 082104 (2020)
T. Uchida, K. Kaneko, S. Fujita, MRS Adv. 3, 171 (2018)
Acknowledgments
This work was, in part, supported by MIC research and development (JPMI00316). H.T. acknowledges JST, the establishment of university fellowships towards the creation of science technology innovation, Grant Number JPMJFS2123.
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Takane, H., Izumi, H., Hojo, H. et al. Effect of dislocations and impurities on carrier transport in α-Ga2O3 on m-plane sapphire substrate. Journal of Materials Research 38, 2645–2654 (2023). https://doi.org/10.1557/s43578-023-01015-8
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DOI: https://doi.org/10.1557/s43578-023-01015-8