Abstract
Lower absorption, lower refractive index and tunable resistance are three advantages of doped silicon oxide containing nanocrystalline silicon grains (nc-SiOx) compared to doped microcrystalline silicon, for the use as p- and n-type layers in thin-film silicon solar cells. In this study we show how optical, electrical and microstructural properties of nc-SiOx layers depend on precursor gas ratios and we propose a growth model to explain the phase separation in such films into Si-rich and O-rich regions as visualized by energy-filtered transmission electron microscopy.
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P. Cuony, M. Marending, D. T. L. Alexander, M. Boccard, G. Bugnon, M. Despeisse and C. Ballif, Appl Phys Lett 97 (21), 213502 (2010).
P. Buehlmann, J. Bailat, D. Domine, A. Billet, F. Meillaud, A. Feltrin and C. Ballif, Appl Phys Lett 91, 143505 (2007).
T. Grundler, A. Lambertz and F. Finger, physica status solidi (c) 7 (3–4), 1085–1088 (2010).
D. Dominé, P. Buehlmann, J. Bailat, A. Billet, A. Feltrin and C. Ballif, Phys Status Solidi-R 2 4, 163–165 (2008).
P. Buehlmann, J. Bailat, A. Feltrin and C. Ballif, Photovoltaic Materials and Manufacturing Issues 1123 (2009).
M. Despeisse, G. Bugnon, A. Feltrin, M. Stueckelberger, P. Cuony, F. Meillaud, A. Billet and C. Ballif, Appl Phys Lett 96, 073507 (2010).
M. Krumrey, M. Hoffmann, G. Ulm, K. Hasche and P. Thomsen-Schmidt, Thin Solid Films 459 (1–2), 241–244 (2004).
C. Droz, E. Vallat-Sauvain, J. Bailat, L. Feitknecht, J. Meier and A. Shah, Sol Energ Mat Sol C 81 1, 61–71 (2004).
G. Lucovsky, J. Yang, S. S. Chao, J. E. Tyler and W. Czubatyj, Phys Rev B 28 6, 3225–3233 (1983).
S. M. Iftiquar, J Phys D Appl Phys 31 14, 1630–1641 (1998).
L. N. He, D. M. Wang and S. Hasegawa, J Non-Cryst Solids 261 (1–3), 67–71 (2000).
F. W. Smith and Z. Yin, J Non-Cryst Solids 137–138 (Part 2), 871–874 (1991).
L. G. Parratt, Phys Rev 99 5, 1635–1635 (1955).
S. Schamm, C. Bonafos, H. Coffin, N. Cherkashin, M. Carrada, G. Ben Assayag, A. Claverie, M. Tence and C. Colliex, Ultramicroscopy 108 4, 346–357 (2008).
G. Nicotra, S. Lombardo, C. Spinella, G. Ammendola, C. Gerardi and C. Demuro, Appl Surf Sci 205 (1–4), 304–308 (2003).
F. Iacona, C. Bongiorno, C. Spinella, S. Boninelli and F. Priolo, J Appl Phys 95 7, 3723–3732 (2004).
A. Matsuda, Thin Solid Films 337 (1–2), 1–6 (1999).
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Cuony, P., Alexander, D.T.L., Löfgren, L. et al. Mixed phase silicon oxide layers for thin-film silicon solar cells. MRS Online Proceedings Library 1321, 1202 (2011). https://doi.org/10.1557/opl.2011.813
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DOI: https://doi.org/10.1557/opl.2011.813