Abstract
Organic disulfide compounds has been proposed as a new class of high-energy storage material. Poly(2,2’-diaminobenzyloxydisulfide), a novel conducting polymer having O-S-S-O bond joined two moieties of anilines, is synthesized both chemically and electrochemically as a new positive storage material. It exhibits conductivity in the region of 10-3 S cm-1 by the fourprobe method and the O-S-S-0 bonds in it are confirmed by Fourie Transform Raman Spectroscopy(FT-RS) and Fourie Transform Infrared Spectroscopy(FT-IR). The poly(2,2’- diaminobenzyloxydisulfide) films are formed by electropolymerization from a AN/THF solution containing 0.1M LiClO4, 0.1MHCl and 0.05 M 2,2’-diaminobenzyloxydisulfide monomer on Pt electrode under continuous cycling between -0.30V and 1.20V vs Ag/AgCl(sat. KCI) at scanning rate 50mv s-1. The cyclic voltammetry shows its electrochemical behaviour is similar to polyaniline. The redox peak current of the cyclic voltammograms increase with increasing of the cyclic numbers.
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S. J. Visco, C. C. Maihe, L. C. De Jonghe and M. B. Amand, J. Electrochem. Soc., 136, p. 661 (1991).
K. Naoi, M. Menda, H. Ooike and N. Oyama, Proc. 31st Bat. Symp. Jpn., p. 31 (1990).
N. Oyama, J. M. Pope and T. Sotomura, J. Electrochem. Soc., 144, p. L47 (1997).
K. C. Gong and W. S. Ma, Mat. Res. Soc. Symp., 461, p. 87 (1997).
L. Yu, X. H. Wang, and J. Li, J. Power Souce, 73, p. 261 (1998).
K. Naoi, K. Kawase, and Y. Inoue, J. Electrochem. Soc., 144, p. L170 (1997).
S. Picar, E. Genies, J. Electroanal. Chem., 408 p. 53 (1996).
K. Naoi, K. Kawase, M. Mori and M. Komiyama, Mat. Res. Soc. Symp., 496, p. 309 (1998).
M. Liu, S. J. Visco and L. C. De Jonghe and M. B. Amand, J. Electrochem. Soc., 138, p. 1891 (1991).
T. Osaka, T. Nakajima, K. Naoi and B. B. Owens, J. Electrochem. Soc., 137, p. 2139 (1990).
D. L. Tardif, C. R. Williams, D. N. Harpp, J. Am. Chem. Soc., 117, p. 9067 (1995).
G. Zotti, S. Cattarub and N. Comisso, J. Electroanal. Chem., 239, p. 387 (1988).
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Su, Y.Z., Ma, W.S. & Gong, K.C. A Novel Conducting Polymer with O-S-S-O Bonds for Positive Material:Poly(2,2′-Diaminobenzyloxydisulfide). MRS Online Proceedings Library 575, 403–408 (1999). https://doi.org/10.1557/PROC-575-403
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DOI: https://doi.org/10.1557/PROC-575-403