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Structural, magnetic and magnetocaloric properties in La0.67(Sr1−xMgx)0.33MnO3 (x = 0, 0.1, 0.3) compounds

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Abstract

The La0.67(Sr1−xMgx)0.33MnO3 (x = 0, 0.1, 0.3) manganites have been prepared by sol–gel method, and the effect of Mg do** on their structure, magnetic and magnetocaloric properties has been researched. All the samples are crystallized in perovskite rhombohedral structure with space group \(R\overline{3}c\). The slight increases in the edge length a and the cell volume with Mg do** indicates the replacement of Mg in Mn-site. The corresponding change of structure parameters, such as Mn–O bond length and Mn–O–Mn bond angle, weakens the exchange coupling between Mn3+ and Mn4+ and results in the decrease in the Curie temperature (TC). With increasing content of Mg, the local inhomogeneity and Griffiths-like phase evolve and induce the deviation of critical exponents from the mean-field model. The existence of these short-range ferromagnetic clusters broadens the temperature range of magnetic transition process, then depresses the magnetic entropy change (|ΔSM|) and flattens the |ΔSM|-T curve. The La0.67(Sr0.7Mg0.3)0.33MnO3 possesses a table-like magnetocaloric effect near room temperature (|ΔSM| is nearly constant of 0.51 ± 0.01 J kg−1 K−1 for field change of 1 T in the temperature range of 277 ~ 302 K), which is beneficial for the Ericsson cycle magnetic refrigerator.

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Data Availability Statement

This manuscript has associated data in a data repository. [Authors’ comment: The datasets analyzed during the current study are available from the corresponding author on reasonable request.]

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Acknowledgements

The work was supported by the National Natural Science Foundation of China (Grant Nos. 51772004 and 51872006), the Anhui Natural Science Foundation (2008085QE279) and the Innovation and Entrepreneurship Training Program for College Students of Anhui University of Technology (Grant No. S202210360179). J.L. also acknowledges the Young Talents and PhD start-up Fund Project from Anhui Jianzhu University (2018QD52).

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Authors and Affiliations

  1. Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Anhui University of Technology, Ministry of Education, Ma’anshan, 243002, China

    Huiyan Zhang, Hailian Wei, Zhiyuan Liu & Ailin **a

  2. Ma’anshan Shuntai Rare Earth New Materials Co., Ltd., Ma’anshan, 243100, China

    Huiyan Zhang & Zhimin Shi

  3. School of Material Science and Engineering, Anhui University of Technology, Ma’anshan, 243002, China

    Huiyan Zhang, Yafang Xu, Jia Tan, Xue Zhang, Binbin Guo, Jiazhe Yan, Hailian Wei, Zhiyuan Liu & Ailin **a

  4. School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei, 230601, China

    Jie Li

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Zhang, H., Xu, Y., Tan, J. et al. Structural, magnetic and magnetocaloric properties in La0.67(Sr1−xMgx)0.33MnO3 (x = 0, 0.1, 0.3) compounds. Eur. Phys. J. Plus 137, 1335 (2022). https://doi.org/10.1140/epjp/s13360-022-03522-9

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