Abstract
The data on generating porous structure from PVF during PVA acetalization is presented. The main parameters comprising the average pore diameter, the ratio of open to closed pores, the apparent density, porosity, and water absorption are estimated. It is shown that the density of PVF samples is about 0.54‒0.58 kg/cm3, and the total porosity is 55–57%. The number of open pores decreases from 38% to 23% when the mixing speed grows from 800 to 1200 rpm. The time dependences of PVF water absorption are obtained and it is established that water is mainly sorbed by open pores, reaching the value of 417%.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS2075113324010039/MediaObjects/13188_2024_2196_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS2075113324010039/MediaObjects/13188_2024_2196_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS2075113324010039/MediaObjects/13188_2024_2196_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS2075113324010039/MediaObjects/13188_2024_2196_Fig4_HTML.png)
REFERENCES
Ushakov, S.N., Polivinilovyi spirt i ego proizvodnye (Polyvinyl Alcohol and Its Derivatives), Moscow–Leningrad: Akad. Nauk SSSR, 1960, vol. 1.
Nagarkar, R. and Patel, J., Polyvinyl alcohol: A comprehensive study, Acta Sci. Pharm. Sci., 2019, vol. 3, no. 4, pp. 34–44.
Muppalaneni, S. and Omidian, H., Polyvinyl alcohol in medicine and pharmacy: A perspective, J. Dev. Drugs, 2013, vol. 2, no. 3, p. 112. https://doi.org/10.4172/2329-6631.1000112
Manzhai, V.N. and Fufaeva, M.S., Dispersity and stability of foams obtained from poly(vinyl alcohol) solution and the properties of resulting foamed cryogels, Colloid J., 2014, vol. 76, no. 4, pp. 455–458. https://doi.org/10.1134/S1061933X14040097
Vilkova, N.G., Mishina, S.I., and Dorchina, O.V., Stability of foams containing diesel fuel, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2018, vol. 61, no. 6, pp. 48–53.
Panov, Yu.T., Nauchnye osnovy sozdaniya penoplastov vtorogo pokoleniya: Monografiya (Scientific Basis for the Creation of Second-Generation Foams: Monograph), Vladimir: Vladimir State Univ., 2003. ISBN 5-89368-379-X
Lomovskoi, V.A., Abaturova, N.A., Lomovskaya, N.Yu., Khlebnikova, O.A., Sakov, D.M., Galushko, T.B., and Barteneva, A.G., Influence of porosity of polyvinylformal structure on its sorption characteristics, Trudy 5-i nauchnoi konferentsii “Fizicheskaya khimiya poverkhnostnykh yavlenii i adsorbtsii,” Ples, 1–6 iyulya 2013 g. (Proc. 5th Sci. Conf. “Physical Chemistry of Surface Phenomena and Adsorption,” Ples, July 1–6, 2013), Ivanovo: Ivanovo State Univ. Chem. Technol., 2014.
Akimova, A.A., Lomovskoi, V.A., and Simonov-Emel’yanov, I.D., Aqueous polyvinyl alcohol solution foaming at different molecular masses, Tonkie Khim. Tekhnol., 2021, vol. 16, no. 4, pp. 337–344. https://doi.org/10.32362/2410-6593-2021-16-4-337-344
Funding
This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors of this work declare that they have no conflicts of interest.
Additional information
Translated by V. Vetrov
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Akimova, A.A., Lomovskoi, V.A. & Simonov-Emel’yanov, I.D. Forming Structure in Porous Polyvinylformal Filters for Selective Water Sorption. Inorg. Mater. Appl. Res. 15, 166–169 (2024). https://doi.org/10.1134/S2075113324010039
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2075113324010039