Abstract
The nickel trimesinate complex with 1,10-phenanthroline has been synthesized by a solvothermal method and used for removing organic dyes, such as Congo red and methylene blue, from their aqueous solutions. The degree of adsorption depends on temperature and reaches 97% for Congo red, while for methylene blue it is about 83%. The mechanisms and characteristic parameters of the adsorption process are analyzed using empirical models of the Langmuir and Freundlich isotherms, of which the most optimal adsorption process is described by the Freundlich model. The calculated thermodynamic parameters point to the spontaneity of the process. The basic stages of thermolysis leading to preparation of the Ni@C–N composite with nickel nanoparticles distributed in the stabilizing nitrogen-doped carbon matrix have been estimated for the synthesized complex.
This is a preview of subscription content, log in via an institution to check access.
REFERENCES
Chen, S., Zhang, J., Zhang, C., Yue, Q., Li, Y., and Li, C., Equilibrium and kinetic studies of methyl orange and methyl violet adsorption on activated carbon derived from Phragmites australis, Desalination, 2010, vol. 252, nos. 1–3, pp. 149–156.
Meng, F., Hong, Z., Arndt, J., Li, M., Zhi, M., Yang, F., and Wu, N., Visible light photocatalytic activity of nitrogen-doped La2Ti2O7 nanosheets originating from band gap narrowing, Nano Res., 2012, vol. 5, no. 3, pp. 213–221.
Soon, A.N. and Hameed, B., Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process, Desalination, 2011, vol. 269, nos. 1–3, pp. 1–16.
Guo, J., Jiang, D., Wu, Y., Zhou, P., and Lan, Y., Degradation of methyl orange by Zn(0) assisted with silica gel, J. Hazard. Mater., 2011, vol. 194, pp. 290–296.
Xu, L., Du, L.-S., Wang, C., and Xu, W., Nanofiltration coupled with electrolytic oxidation in treating simulated dye wastewater, J. Membr. Sci., 2012, vol. 409, pp. 329–334.
Hu, J., Yu, H., Dai, W., Yan, X., and Hu, X., and Huang, H., Enhanced adsorptive removal of hazardous anionic dye “congo red” by a Ni/Cu mixed-component metal–organic porous material, RSC Adv., 2014, vol. 4, no. 66, pp. 35124–35130.
Arami, M., Limaee, N.Y., Mahmoodi, N.M., and Tabrizi, N.S., Removal of dyes from colored textile wastewater by orange peel adsorbent: Equilibrium and kinetic studies, J. Colloid Interface Sci., 2005, vol. 288, no. 2, pp. 371–376.
Dzhardimalieva, G., Baimuratova, R., Knerelman, E., Davydova, G., Kudaibergenov, S., Kharissova, O., Zhinzhilo, V., and Uflyand, I., Synthesis of copper(II) trimesinate coordination polymer and its use as a sorbent for organic dyes and a precursor for nanostructured material, Polymers, 2020, vol. 12, no. 5, p. 1024.
Dzhardimalieva, G.I. and Uflyand, I.E., Design and synthesis of coordination polymers with chelated units and their application in nanomaterials science, RSC Adv., 2017, vol. 7, pp. 42242–42288.
Yang, Y., Ren, G., Li, W., Gu, D., Liang, Z., Liu, Y., and Pan, Q., Three coordination complexes based on mixed ligand strategy: Coordination diversities and nitrobenzene detections, Polyhedron, 2020, vol. 185, p. 114599.
Dzhardimalieva, G.I. and Uflyand, I.E., Chemistry of Polymeric Metal Chelates, Cham: Springer, 2018.
Uflyand, I.E., Zhinzhilo, V.A., Dzhardimalieva, G.I., Knerelman, E.I., Davydova, G.I., and Shunina, I.G., Synthesis and properties of copper trimesinate complexes with polypyridine ligands, Russ. J. Gen. Chem., 2020, vol. 90, no. 10, pp. 1884–1891.
Kharisov, B.I., Kharissova, O.V., and Méndez, U.O., Coordination and organometallic compounds as precursors of classic and less-common nanostructures: Recent advances, J. Coord. Chem., 2013, vol. 66, no. 21, pp. 3791–3828.
Song, Y., Li, X., Sun, L., and Wang, L., Metal/metal oxide nanostructures derived from metal–organic frameworks, RSC Adv., 2015, vol. 5, no. 10, pp. 7267–7279.
Aljeboree, A.M., Alshirifi, A.N., and Alkaim, A.F., Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon, Arabian J. Chem., 2017, vol. 10, pp. S3381–S3393.
Saghir, S., Fu, E., and **ao, Z., Synthesis of CoCu-LDH nanosheets derived from zeolitic imidazole framework-67 (ZIF-67) as an efficient adsorbent for azo dye from waste water, Microporous Mesoporous Mater., 2020, vol. 297, p. 110010.
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Weinheim: Wiley, 2009.
Hamdaoui, O., Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick, J. Hazard. Mater., 2006, vol. 135, pp. 264–273.
Jenkins, R. and Snyder, R.L., Chemical Analysis: Introduction to X-Ray Powder Difractometry, Weinheim: Wiley, 1996.
Yudanova, L.I., Logvinenko, V.A., Yudanov, N.F., Rudina, N.A., Ishchenko, A.V., Semyannikov, P.P., Sheludyakova, L.A., Alferova, N.I., Romanenko, A.I., and Anikeeva, O.B., Preparation of metal–polymer composites through the thermolysis of Fe(II), Co(II), and Ni(II) maleates, Inorg. Mater., 2013, vol. 49, no. 10, pp. 1055–1060.
Uflyand, I.E., Zhinzhilo, V.A., and Dzhardimalie-va, G.I., Coordination polymer based on nickel(II) maleate and 4′-phenyl-2,2′:6′,2′′-terpyridine: Synthesis, crystal structure and conjugated thermolysis, J. Inorg. Organomet. Polym. Mater., 2020, vol. 30, no. 2, pp. 965–975.
Chaudhuri, R.G. and Paria, S., Core/shell nanoparticles: classes, properties, synthesis mechanisms, characterization, and applications, Chem. Rev., 2012, vol. 112, no. 4, pp. 2373–2433.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by N. Rukk
Rights and permissions
About this article
Cite this article
Zhinzhilo, V.A., Slepova, K.V. & Uflyand, I.E. A Mixed-Ligand Complex of Nickel Trimesinate with 1,10-Phenanthroline as an Adsorbent for Organic Dyes and a Precursor of Nanostructured Materials. Inorg. Mater. Appl. Res. 14, 341–348 (2023). https://doi.org/10.1134/S2075113323020491
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2075113323020491