Log in

Gas chromatography investigations of thermodynamics of adsorption of organic compound vapors on carbon adsorbent modified by β-cyclodextrin derivatives

  • Separation Processes at Interfaces: Chromatography
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The adsorption of organic-compound vapors of various structures and polarities on carbon adsorbent modified by permethylated and perbenzylated β-cyclodextrin is investigated using gas chromatography. The obtained thermodynamic properties are compared for adsorption on initial carbon adsorbent and two modified adsorbents. The influence of molecular structure of the studied sorbates and substituent groups in cyclodextrin molecules on adsorption is considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Mraz, J., Feltl, L., and Smolkova-Keulemansova, E., J. Chromatogr., 1984, vol. 286, p. 17.

    Article  CAS  Google Scholar 

  2. Smolkova-Keulemansova, E., Feltl, L., and Krysl, S., J. Inclusion Phenom., 1985, vol. 3, p. 183.

    Article  CAS  Google Scholar 

  3. Feltl, L., Tajovska, P., and Smolkova-Keulemansova, E., J. Chromatogr., 1990, vol. 520, p. 105.

    Article  CAS  Google Scholar 

  4. Kalashnikova, E.V., Shcherbakova, K.D., Smolkova-Keulemansova, E. et al., Chromatographia, 1992. vol. 33, nos. 1/2, p. 10.

    Article  CAS  Google Scholar 

  5. Kudryashov, S.Yu., Kopytin, K.A., Pavlov, M.Yu., et al., J. Phys. Chem., 2010, vol. 84, no. 3, p. 570.

    Google Scholar 

  6. Lopatkin, A.A., J. Phys. Chem., 1997, vol. 71, no. 5, p. 916.

    CAS  Google Scholar 

  7. Lopatkin, A.A., Teoreticheskie osnovy fizicheskoi adsorbtsii (Theoreical Foundations of Physical Adsorption), Moscow: MGU, 1983.

    Google Scholar 

  8. Reznikov, S.A., J. Phys. Chem., 1994, vol. 68, no. 2, p. 382.

    CAS  Google Scholar 

  9. Yagodovskii, V.D. Statisticheskaya termodinamika v fizicheskoi khimii (Statistical Thermodynamics in Physical Chemistry), Moscow: BINOM, 2005.

    Google Scholar 

  10. Karnaukhov, A.P., Adsorbtsiya. Tekstura dispersnykh i poristykh materialov (Adsorption. Texture of Dispersive and Porous Materials), Novosibirsk: Nauka, 1999.

    Google Scholar 

  11. Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, London: Academic, 1967.

    Google Scholar 

  12. Sigma-Aldrich, Co., Supelco Bulletin 877, CHiral Cyclodextrin Capillary GC Columns.

  13. Kalashnikova, E.V., Kiselev, A.V., Petrova, R.S., et al., Chromatograpia, 1979, vol. 12, no. 2, p. 800.

    Google Scholar 

  14. Avgul’, N.N., Kiselev, A.V., and Poshkus, D.P. Adsorbtsiya gazov i parov na odnorodnykh poverkhnostyakh (Adsorption of Gases and Vapors on Homogeneous Surfaces), Moscow: Khimiya, 1975, p. 369.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. A. Kopytin.

Additional information

Original Russian Text © K.A. Kopytin, S.Yu. Kudryashov, A.R. Khafiyatova, Z.P. Belousova, L.A. Onuchak, 2011, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2011, Vol. 47, No. 6, pp. 580–585.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kopytin, K.A., Kudryashov, S.Y., Khafiyatova, A.R. et al. Gas chromatography investigations of thermodynamics of adsorption of organic compound vapors on carbon adsorbent modified by β-cyclodextrin derivatives. Prot Met Phys Chem Surf 47, 707–712 (2011). https://doi.org/10.1134/S2070205111060074

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205111060074

Keywords

Navigation