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Catalytic Hydrogenation of Carbon Dioxide as a Method to Produce Valuable Chemicals

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

The aim of this review is to summarize and comparatively analyze recent reports on studying carbon dioxide conversion to methanol, dimethyl ether, and C2+ hydrocarbons, in particular, olefins, by catalytic hydrogenation. It is shown that the main approaches to providing high activity and selectivity of these processes are the targeted design of catalysts and the selection of conditions for hydrogenation processes, in particular, the use of supercritical CO2 and procedures that are alternative to conventional physicochemical methods for CO2 activation (electrocatalysis, photocatalysis).

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  1. https://ru.wikipedia.org/wiki/%D0%A3%D0%B3%D0%BB%D-0%B5%D0%BA%D0%B8%D1%81%D0%BB%D1%8B%D0%B9_%D0%B3%D0%B0%D0%B7_%D0%B2_%D0%B0%D1%82%D0%BC%D0%BE%D1%81%D1%84%D0%B5%D1%80%D0%B5_%D0%97%D0%B5%D0%BC%D0%BB%D0%B8

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This work was performed under a state task of the Ministry of Science and Higher Education of the Russian Federation (subject no. AAAA-A19-119022690098-3).

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  1. Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    I. A. Makaryan, I. V. Sedov & V. I. Savchenko

  2. National Research University Higher School of Economics, 101000, Moscow, Russia

    I. V. Sedov

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Makaryan, I.A., Sedov, I.V. & Savchenko, V.I. Catalytic Hydrogenation of Carbon Dioxide as a Method to Produce Valuable Chemicals. Catal. Ind. 16, 14–38 (2024). https://doi.org/10.1134/S2070050424010045

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