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The Influence of Metal Sludge on the Oxidative Destruction of Low-Density Polyethylene

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Abstract

The work investigated the effect of three types of metal sludge as an oxo-decomposing additive to polyethylene. Mechanical characteristics were studied before and after complex climatic exposure in a three-factor climate chamber (heat, light, humidity). Using infrared spectroscopy, an accumulation of oxygen-containing groups in polyethylene with sludge was shown in comparison with pure polyethylene after climatic tests. The catalytic effect of two metal slurries on the oxidative destruction of polyethylene was shown.

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REFERENCES

  1. A. A. Shabarin, A. M. Kuz’min, I. A. Shabarin, and V. V. Butyaikin, “Polymer composites based on polyolefins and finely ground barley straw,” Ekolog. Prom-st’ Rossii 26, 4–9 (2022).

    Google Scholar 

  2. P. V. Pantyukhov, T. V. Monakhova, N. N. Kolesnikova, A. A. Popov, and S. G. Nikolaeva, “Destruction of composite materials made of LDPE and lignocellulosic fillers,” J. Balkan Tribol. Assoc. 19, 467–475 (2013).

    CAS  Google Scholar 

  3. O. M. D’yakonov. “Sludge from metalworking production. Part 1: Chemical composition,” Lit’e Metallurg., Nos. 1–2, 154–159 (2010).

    Google Scholar 

  4. E. T. Denisov and N. M. Emanuel’, “Catalysis by metal salts of variable valence in liquid-phase oxidation reactions,” Usp. Khim. 29, 1409–1438 (1960).

    Article  CAS  Google Scholar 

  5. Yu. K. Lukanina, N. N. Kolesnikova, A. A. Popov, and A. V. Khvatov, “Metal-containing additives for polyethylene oxo-degradation,” Russ. J. Phys. Chem. B 13, 369–373 (2019).

    Article  CAS  Google Scholar 

  6. E. Chiellini, A. Corti, S. D’Antone, and D. M. Wiles. “Oxobiodegradable Polymers: Present Status and Future Perspectives,” in Biodegradable Polymers: Isolation, Synthesis, Characterization and Applications, Ed. by A. Lendlein and A. Sisson (Wiley Online Library, 2011), Ch. 16, pp. 376–398.

    Google Scholar 

  7. E. V. Vorob’eva, “Thermal-oxidative resistance of polyethylene films containing copper and ascorbic acid,” Zh. Prikl. Khim. 94, 1155–1163 (2021).

    Google Scholar 

  8. S. V. Shtepa and M. V. Anisimov, RU Patent No. 2677149 (2019).

  9. L. Forsgren, E. C. B. Noyan, A. Vega, Y. Nazdaneh, and A. Boldizar, “The thermo-oxidative durability of polyethylene reinforced with wood-based fibres,” Polym. Degrad. Stab. 181, 109374 (2020).

    Article  CAS  Google Scholar 

  10. W. Teguh, D. A. Astuti, K. G. Wiryawan, I. Sugoro, and A. Jayanegara, “Fourier transform mid-infrared (FTIR) spectroscopy to identify tannin compounds in the panicle of sorghum mutant lines,” IOP Conf. Ser.: Mater. Sci. Eng. 546, 042045 (2019).

  11. J. Oliveira, P. L. Almeida, and R. G. Sobral, “Marine-derived actinomycetes: biodegradation of plastics and formation of PHA bioplastics—a circular bioeconomy approach,” Mar. Drugs 20, 760 (2022).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  12. L. A. Yakovishin, E. V. Tkachenko, and Yu. V. Tolstenko, “Using the IR spectroscopy method with an ATR attachment for the analysis of composite materials based on phenylone C-1,” Uch. Zap. Krym Fed. Univ. Biol. Khim. 5, 230–237 (2019).

    Google Scholar 

  13. V. V. Shertukde, R. S. Tarade, and S. V. Patil, “Comparative study of surface morphology and spectroscopic analysis for plasma and ammonium persulphate treated polyethylene film for water based ink printing,” Res. Rev. Polym. 6, 110–117 (2015).

    Google Scholar 

  14. C. Sandt, J. Waeytens, A. Deniset-Besseau, and C. Nielsen-Leroux, “Use and misuse of FTIR spectroscopy for studying the bio-oxidation of plastics,” Spectrochim. Acta, Part A 258, 119841 (2021).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The equipment of the Center for Collective Use of the Plekhanov Russian University of Economics and Center for Collective Use of the Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences.

Funding

The work was carried out with the financial support of the Plekhanov Russian University of Economics.

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Authors and Affiliations

  1. Plekhanov Russian University of Economics, 117997, Moscow, Russia

    M. Yu. Guivan, V. A. Ovchinnikov, E. A. Mamin, P. V. Pantyukhov, E. E. Mastalygina, Z. R. Abushakhmanova, B. B. Khaidarov & A. A. Popov

  2. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119334, Moscow, Russia

    V. A. Ovchinnikov

  3. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334, Moscow, Russia

    E. A. Mamin, P. V. Pantyukhov, E. E. Mastalygina, Z. R. Abushakhmanova & A. A. Popov

  4. University of Science and Technology “MISiS”, 119049, Moscow, Russia

    B. B. Khaidarov

Authors
  1. M. Yu. Guivan
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  2. V. A. Ovchinnikov
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  3. E. A. Mamin
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  4. P. V. Pantyukhov
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  5. E. E. Mastalygina
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  6. Z. R. Abushakhmanova
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  7. B. B. Khaidarov
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  8. A. A. Popov
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Corresponding author

Correspondence to M. Yu. Guivan.

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Translated by M. Drozdova

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Guivan, M.Y., Ovchinnikov, V.A., Mamin, E.A. et al. The Influence of Metal Sludge on the Oxidative Destruction of Low-Density Polyethylene. Polym. Sci. Ser. D 17, 502–506 (2024). https://doi.org/10.1134/S1995421224700850

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  • DOI: https://doi.org/10.1134/S1995421224700850

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