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Thermal Oxidation of Ethylene Copolymer with Vinyl Acetate in the Presence of Petroleum Polymer Resin

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Abstract

The influence of petroleum resin on the thermal oxidation of an ethylene copolymer with vinyl acetate was studied with differential scanning calorimetry, FTIR infrared spectroscopy, and physicomechanical tests. We found that the introduction of PPR into EVAC inhibits the accumulation of oxygen-containing groups in the polymer. The use of the resin combined with an Irganox 1010 primary antioxidant makes it possible to maintain the performance of a material after holding at higher temperature for 3 h at a significantly higher level than in the case of only Irganox 1010.

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REFERENCES

  1. J. Liang, S. Chang, and N. Feng, “Effect of C5 petroleum resin content on dam** behavior, morphology, and mechanical properties of BIIR/BR vulcanizates,” J. Appl. Polym. Sci. 130, 510–515 (2013).

    Article  CAS  Google Scholar 

  2. V. G. Bondaletov, L. I. Bondaletova, and Yu. B. Varakina, “Study of oil-resin compositions, including petroleum polymer resins modified with vinyl butyl ether,” Izv. Tomsk. Politekh. Univ., No. 3, 157–161 (2011).

    Google Scholar 

  3. A. Kh. Gumarov, R. M. Garipov, and O. V. Stoyanov, “Modification of coatings based on chlorosulfonated polyethylene with petroleum resins,” Vestn. Kazan. Tekhnol. Univ., No. 9, 71–73 (2011).

    Google Scholar 

  4. S. A. Perfilyeva, Zh. S. Shashok, E. P. Uss, et al., “Study of the influence of petroleum polymer resins on the properties of unfilled elastomeric compositions,” Trudy Bryansk Gos. Tekh. Univ. Ser 2 No. 1, 92–98 (2018).

    Google Scholar 

  5. Yu. V. Dumskii, G. F. Cherednikova, and S. Yu. Dumskii, “Petroleum polymer resins and new possibilities for their use,” Lakokrasochnye Mater. Primenenie, No. 10, 8–12 (2007).

    Google Scholar 

  6. E. Kraus, L. Orf, V. Sitnik, et al., “Composition and surface energy characteristics of new petroleum resins,” Polym. Eng. Sci. 57, 1028–1032 (2017).

    Article  CAS  Google Scholar 

  7. R. A. Perelygina, I. A. Starostina, A. R. Efimova, et al., “Comparative analysis of surface and thermal properties of oil—polymer resins,” Polym. Sci., Ser. D 11, 369–373 (2018).

    CAS  Google Scholar 

  8. R. A. Perelygina, I. A. Starostina, A. S. Ziganshina, et al., “Modification of ethylene and vinyl acetate copolymers with petroleum resins,” Polym. Sci., Ser. D 12, 372–375 (2019).

    CAS  Google Scholar 

  9. L. Orf and I. Starostina, et al., “Composite materials based on polyolefins with new petroleum resins,” Polym. Eng. Sci., No. 58, 2288–2292 (2018).

    Article  Google Scholar 

  10. A. N. Chernaya, Candidate’s Dissertation in Engineering (Voronezh, 2011).

  11. I. G. Usacheva, A. D. Yakovlev, O. A. Novozhilova, A. V. Pushkov, V. G. Sidorov, and L. I. Kutyanin, Avt. Svid. SSSR No. 1712379 (1992).

  12. E. V. Vorobyova, “Changes in the structure of the phenolic antioxidant Irganox 1010 in the composition of the zinc-containing polymer composite with cyclic thermal effects,” Theor. Appl. Sci., No. 67, 232–239 (2018).

    Article  Google Scholar 

  13. Yu. A. Shlyapnikov, S. G. Kiryushkin, and A. P. Mar’in, Antioxidant Stabilization of Polymers (Khimiya, Moscow, 1986) [in Russian].

    Google Scholar 

  14. L. I. Lugova, G. S. Popova, F. O. Pozdnyakova, et al., “Study of the mechanism of thermal-oxidative degradation of an ethylene-vinyl acetate copolymer, Vysokomol. Soedin., No. 8, 614–617 (1975).

    Google Scholar 

  15. A. L. Goldenber, L. N. Pirozhnaya, G. S. Popova, and L. I. Tarutina, “Molecular Spectrscopy,” in Collection of Papers (1960), pp. 131–136.

  16. A. Kh. Kuptsov and G. N. Zhizhin, Fourier Raman and Fourier IR Spectra of Polymers (Tekhnosfera, Moscow, 2013) [in Russian].

    Google Scholar 

  17. L. Bellami, The Infrared Spectra of Complex Molecules (Springer, 1980; Inostrannaya Literatura, 1963).

  18. L. I. Tarutina and F. O. Pozdnyakova, Spectral Analysis of Polymers (Khimiya, Leningrad, 1986) [in Russian].

    Google Scholar 

  19. A. A. Lyapkov, V. G. Bondaletov, E. I. Mel’nik, et al., “Study of the polymerization of dicyclopentadiene in the presence of catalytic systems based on TiCl 4,” Izv. Tomsk. Politekh. Univ., No. 3, 105–112 (2013).

    Google Scholar 

  20. Yu. V. Dumskii, B. I. No, and G. M. Butov, Chemistry and Technology of Petroleum Resins (Khimiya, Moscow, 1999) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Kazan National Research Technological University, 420015, Kazan, Russia

    R. A. Perelygina, I. A. Starostina, A. I. Zagidullin, R. M. Garipov, S. N. Rusanova & O. V. Stoyanov

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  1. R. A. Perelygina
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  2. I. A. Starostina
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  3. A. I. Zagidullin
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  4. R. M. Garipov
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  5. S. N. Rusanova
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  6. O. V. Stoyanov
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Correspondence to O. V. Stoyanov.

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Translated by A. Tulyabaew

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Perelygina, R.A., Starostina, I.A., Zagidullin, A.I. et al. Thermal Oxidation of Ethylene Copolymer with Vinyl Acetate in the Presence of Petroleum Polymer Resin. Polym. Sci. Ser. D 16, 340–344 (2023). https://doi.org/10.1134/S1995421223020296

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  • DOI: https://doi.org/10.1134/S1995421223020296

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