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Synthesis and Properties of Phenol–Formaldehyde Resins from Thermal-Processing Products of Wood

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Abstract

We present a laboratory study confirming that phenol in phenol–formaldehyde resins can be replaced with deep thermal-processing products of raw wood. Operating conditions of synthesis are described, and a synthetic recipe is given. The synthesized resins were analyzed by physicochemical methods (IR spectroscopy, TGA, and the tensile strength test). The study revealed that such a replacement requires no considerable changes to be made in operating parameters of the current synthetic process for phenol–formaldehyde resins and allows one to obtain a glue based on this resin with a shear strength equal to 1.58 MPa, which meets specifications of the state standard.

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REFERENCES

  1. A. Volkov, Plywood Handbook (Politekh. Univ., St. Petersburg, 2010) [in Russian].

    Google Scholar 

  2. G. Doronin, Synthetic Resins in Woodworking, 2nd ed. (Lesnaya Prom-st’, Moscow, 1987) [in Russian].

    Google Scholar 

  3. E. N. Medvedeva, “Synthesis of lignin-containing phenol-formaldehyde resins,” Khim. Rastitelnogo Syrya, No. 1, 51–54 (2000).

    Google Scholar 

  4. R. M. Khaziakhmedova, A. N. Grachev, S. A. Pushkin, and V. N. Bashkirov, “Physical and mechanical properties of sawdust concrete with torrefied wood filler,” Derevoobrabat. Prom-st’, No. 3, 54–60 (2019).

    Google Scholar 

  5. A. Knop and L. A. Pilato, Phenolic Resins: Chemistry, Applications and Performance (Springer, Berlin, 1985).

    Book  Google Scholar 

  6. A. I. Valiullina, A. N. Grachev, A. R. Valeeva, G. M. Bikbulatova, S. A. Zabelkin, and V. N. Bashkirov, “The use of biopolyols obtained from liquid birch sawdust pyrolysis products as a renewable component in the production of rigid polyurethane foam,” Polym. Sci., Ser. D 15, 300—305 (2022).

    CAS  Google Scholar 

  7. G. M. Faizrakhmanova, S. A. Zabelkin, A. N. Grachev, V. N. Bashkirov, and A. A. Makarov, “The use of wood pyrolysis liquid to obtain a binder component for road construction,” Vestn. Kazan. Tekhnol. Univ. 16, 312–314 (2013).

    CAS  Google Scholar 

  8. S. A. Zabelkin, A. N. Grachev, G. M. Bikbulatova, A. E. Yakovleva, A. A. Makarov, and V. N. Bashkirov, “Resole-type phenol–formaldehyde resin with neutralized liquid products of fast pyrolysis of birch wood,” Polym. Sci., Ser. D 11, 131–134 (2018).

    CAS  Google Scholar 

  9. V. A. Belyi, “Study of the acid-base properties of lignin using pK spectroscopy,” in Proceedings of the 20th All-Russian Conference “Structure and Dynamics of Molecular Systems”, Yal’chik, 2013.

  10. A. R. Valeeva, A. I. Sabirzyanova, G. M. Bikbulatova, and S. A. Zabelkin, “The strength of phenol-formaldehyde resin modified with liquid products of wood pyrolysis depending on the use of its various fractions,” in Proceedings of 22nd International Scientific and Practical Conference of Students and Young Scientists “Chemistry and Chemical Technology in the 21st century” (Nats. Issled. Tomsk. Politekh. Univ., 2021), pp. 240–241.

  11. A. Stucker, F. Schutt, B. Saake, and R. Lehnen, “Lignins from enzymatic hydrolysis and alkaline extraction of steam refined poplar wood. Utilization in lignin-phenol-formaldehyde resins,” Ind. Crops Prod. 85, 300–308 (2016).

    Article  Google Scholar 

  12. A. R. Valeeva, A. I. Valiullina, S. A. Zabelkin, et al., “Influence of pressing time and storage time on the strength of phenol-formaldehyde resin with 40% replacement of synthetic phenol by liquid pyrolysis products of wood waste,” Sistemy. Metody. Tekhnol., No. 3, 116–121 (2021). https://doi.org/10.18324/2077-5415-2021-3-116-121

    Article  Google Scholar 

  13. D. S. Fardhyanti, “Novia Noor Cahyani improving the quality of bio-oil produced from rice husk pyrolysis by extraction of its phenolic compounds,” Jurnal Bahan Alam Terbarukan JBA 8, 90–100 (2020).

    Article  Google Scholar 

  14. M. A. Varfolomeev, V. N. Emelyanenko, T. R. Musin, A. V. Gerasimov, D. K. Nurgaliev, A. N. Grachev, A. A. Makarov, and S. A. Zabelkin, “Thermal analysis and calorimetric study of the combustion of hydrolytic wood lignin and products of its pyrolysis,” Chem. Technol. Fuels and Oils 51, 140–145 (2015).

    Article  CAS  Google Scholar 

  15. K. N. Sitdykova, R. M. Khaziakhmedova, and R. M. Grachev, “Fast ablative pyrolysis,” in Proceedings of the All-Russian Scientific Conference “Actual Problems of Polymer Science–2018”, Kazan, 2018 (Kazan Nats. Issled. Politekh. Univ., 2018), p. 25.

  16. https://energolesprom.ru/.

  17. S. Zabelkin, A. Valeva, A. Sabirzyanova, A. Grachev, and V. Bashkirov, “Neutrals influence on the water resistance coefficient of phenol-formaldehyde resin modified by wood pyrolysis liquid products,” Biomass Conversion and Biorefinery, 12, 5563–5570 (2022).

    Article  CAS  Google Scholar 

  18. GOST 9624–2009. Laminated Glued Wood (Izd. Standartov, Moscow, 2009) [in Russian].

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Authors and Affiliations

  1. Kazan National Research Technological University, 420015, Kazan, Russia

    A. I. Valiullina, A. N. Grachev, A. R. Valeeva, S. A. Zabelkin, G. M. Bikbulatova, R. M. Khaziakhmedova & V. N. Bashkirov

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  1. A. I. Valiullina
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  2. A. N. Grachev
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  3. A. R. Valeeva
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  4. S. A. Zabelkin
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  5. G. M. Bikbulatova
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  6. R. M. Khaziakhmedova
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  7. V. N. Bashkirov
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Correspondence to A. I. Valiullina.

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Translated by K. Utegenov

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Valiullina, A.I., Grachev, A.N., Valeeva, A.R. et al. Synthesis and Properties of Phenol–Formaldehyde Resins from Thermal-Processing Products of Wood. Polym. Sci. Ser. D 16, 43–50 (2023). https://doi.org/10.1134/S1995421223010343

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  • DOI: https://doi.org/10.1134/S1995421223010343

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