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The Influence of Association of Reagents on the Polycondensation of Epichlorhydrin and 1,3-Bis(dimethylamino)propanol-2 in Water

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Abstract

In the preparation of polyammonium resin by polycondensation of equimolar amounts of epichlorohydrin and 1,3-bis(dimethylamino)propanol-2 in aqueous solutions, a nonstandard concentration effect was revealed, which manifested itself in a sharp increase in the reduced reaction rate, equilibrium conversion, and achievable molecular weight of the polymer at initial concentrations of reagents close to 2.0 mmol/g (the concentration range of 0.5–3.5 mmol/g was studied). The data obtained can be used in the search for additional economical resources to improve the technical and economic indicators of organic synthesis processes.

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Funding

The presented results were obtained as part of the implementation of a state order in the field of scientific work, topic no. FSWE-2020-0008.

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Authors and Affiliations

  1. Alekseev Nizhny Novgorod State Technical University, 603950, Nizhny Novgorod, Russia

    O. A. Kazantsev, K. V. Shirshin, D. S. Baruta, E. A. Bolshakova, M. V. Savinova & I. R. Arifullin

  2. Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant, 60600, Dzerzhinsk, Nizhny Novgorod, Russia

    K. V. Shirshin

Authors
  1. O. A. Kazantsev
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  2. K. V. Shirshin
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  3. D. S. Baruta
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  4. E. A. Bolshakova
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  5. M. V. Savinova
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  6. I. R. Arifullin
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Corresponding author

Correspondence to K. V. Shirshin.

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Translated by M. Drozdova

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Kazantsev, O.A., Shirshin, K.V., Baruta, D.S. et al. The Influence of Association of Reagents on the Polycondensation of Epichlorhydrin and 1,3-Bis(dimethylamino)propanol-2 in Water. Polym. Sci. Ser. D 15, 581–585 (2022). https://doi.org/10.1134/S1995421222040323

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  • DOI: https://doi.org/10.1134/S1995421222040323

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