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The Rate of the Oxygen Absorption by the Styrene Epoxide–p-Toluene Sulfonic Acid Double System Depending on the Structure of the Aliphatic Tail of the Alcohol Solvent

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS, CATALYSIS
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Abstract

Oxygen oxidation of the styrene epoxide (SE)–p-toluene sulfonic acid (TSA) double system (DS) in solutions of three primary alcohols, 1-octanol (OCT), n-butanol (BUT), and ethanol (ET), is studied. The corresponding concentration expressions of oxidation rates are as follows: VOCT = k [SE]0 [TSA]1, VBUT = k [SE]0 [TSA]0.63, and VET = k [SE]0 [TSA]0.7 at [SE] \( \gg \) [TSA]. The proximity of the oxidation activation energies in three alcohols contrasts with the difference in the oxidation rates: the oxidation rate in ET is three times the rate in n-butanol and thirty times the oxidation rate in 1-octanol.

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This study was carried out on the topic of a state assignment (topic no. AAAA–A19–119071890015–6).

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  1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Russia

    V. M. Solyanikov & L. V. Petrov

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  1. V. M. Solyanikov
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Solyanikov, V.M., Petrov, L.V. The Rate of the Oxygen Absorption by the Styrene Epoxide–p-Toluene Sulfonic Acid Double System Depending on the Structure of the Aliphatic Tail of the Alcohol Solvent. Russ. J. Phys. Chem. B 17, 1259–1264 (2023). https://doi.org/10.1134/S1990793123060234

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