Abstract
Optical absorption spectra of the Bi+ impurity center isomorphically substituting Cs+ in CsCdBr3 are recorded over a wide temperature range (from 3.2 to 300 K). An analysis of the vibrational degrees of freedom of the impurity center within the framework of the model of a single effective phonon mode yields various spectroscopic parameters of the optical transition in the Bi+ ion, such as the zero-phonon transition energy, Huang–Rhys parameter, and effective phonon energy. The results are used to compare the properties of the Bi+ center in various crystalline matrices.
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Original Russian Text © A.N. Romanov, K.N. Boldyrev, D.N. Vtyurina, E.V. Haula, D.P. Shashkin, N.A. Pimkin, M.S. Kuznetsov, I.S. Lisitsky, V.N. Korchak, 2016, published in Khimicheskaya Fizika, 2016, Vol. 35, No. 11, pp. 3–8.
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Romanov, A.N., Boldyrev, K.N., Vtyurina, D.N. et al. Optical absorption spectra of the Bi+ impurity center in CsCdBr3 ternary bromide. Russ. J. Phys. Chem. B 10, 897–901 (2016). https://doi.org/10.1134/S1990793116060099
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DOI: https://doi.org/10.1134/S1990793116060099