Abstract
The Kola geotectonic province in the northeastern Fennoscandian Shield accommodates a significant number of alkaline rock massifs differing in age. They are of mantle and mantle-crustal origin (alkali and nepheline syenites, carbonatites) and related to crustal sources (Neoarchean alkali granites). Among them, the Neoarchean Sakharjok nepheline syenite massif is related to the oldest intrusions of this kind bearing yttrium-zirconium mineralization. The crystallization of alkali syenite pertaining to the first intrusive phase of the intrusive Sakharjok massif is dated to 2645 ± 7 Ma, and this implies that this syenite postdated alkali granites (2.66–2.67 Ga). To date the yttrium-zirconium ore, we applied the local U-Pb method to zircon crystals occurring in the mineralized block hosted in nepheline syenite. The earliest fragments of zircon crystallized 1832 ± 7 Ma ago; the age of metamorphism is estimated at 1784 ± 13 Ma. These dates indicate the Paleoproterozoic age of the yttrium-zirconium mineralization, which was formed as a product of fluid reworking of the Neoarchean nepheline syenite of the Sakharjok massif.
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References
Balashov, Yu.A., Paleoproterozoic geochronology of the Pechenga-Varzuga structure, Kola Peninsula, Petrology, 1996, vol. 4, no. 1, pp. 1–22.
Batieva, I.D. and Bel’kov, I.V., Sakhariokskii shchelochnoi massiv, slagayushchie ego porody i mineraly (The Sakaharjok Alkaline Massif, Its Rocks and Minerals), Apatity: Kola Branch, USSR Acad. Sci., 1984.
Bayanova, T.B., Vozrast repernykh geologicheskikh kompleksov Kol’skogo regiona i dlitel’nost’ protsessov magmatizma (Age of Reference Geological Complexes of the Kola Region and Duration of Geological Processes), St. Petersburg: Nauka, 2004.
Belousova, E.A. and Griffin, W.L., and O’Reilly, S.Y., and Fisher, N.I., Igneous zircon: Trace element composition as an indicator of source rock type, Contrib. Mineral. Petrol., 2002, vol. 143, pp. 602–622.
Chen, R.-X., Zheng, Y.-F., and **e, L., Metamorphic growth and recrystallization of zircon: Distinction by simultaneous in-situ analyses of trace elements, U-Th-Pb and Lu-Hf isotopes in zircons from eclogite-facies rocks in the Sulu Orogen, Lithos, 2010, vol. 114, pp. 132–154.
Hinton, R.W. and Upton, B.G.J., The chemistry of zircon: variations within and between large crystals from syenite and alkali basalt xenoliths, Geochim. Cosmochim. Acta, 1991, vol. 55, pp. 3287–3302.
Hoskin, P.W.O., Minor and trace element analysis of natural zircon (ZrSiO4) by SIMS and laser ablation ICPMS: A consideration and comparison of two broadly competitive techniques, J. Trace Microprobe Tech., 1998, vol. 16, pp. 301–326.
Hoskin, P.W.O., Trace-element composition of hydrothermal zircon and the alteration of Hadean zircon from the Jack Hills, Australia, Geochim. Cosmochim. Acta, 2005, vol. 69, no. 3, pp. 637–648.
Hoskin P.W.O. and Schaltegger U. The composition of zircon and igneous and metamorphic petrogenesis, Rev. Miner. Geochim., 2003. vol. 53. pp. 27–62.
Kinny, P.D., Compston, W., and Williams, I.S., A reconnaissance ion-probe study of hafnium isotopes in zircons, Geochim. Cosmochim. Acta, 1991, vol. 55, pp. 849–859.
Lee, J.K.W., Williams, I.S., and Ellis, D.J., Pb, U and Th diffusion in natural zircon, Nature, 1997, vol. 390, pp. 159–161.
Lyalina, L.M., Zozulya, D.R., and Savchenko, E.E., Multiple crystallization of zircon in the Sakharjok rare-earth element-zirconium deposit, Kola Peninsula, Dokl. Earth Sci., 2010, vol. 430, no. 1, pp. 120–124.
McDonough, W.F. and Sun, S.S., The composition of the Earth, Chem. Geol., 1995, vol. 120, pp. 223–253.
Mitrofanov, F.P., Zozulya, D.R., Bayanova, T.B., and Levkovich, N.V., The world’s oldest anorogenic alkali granitic magmatism in the Keivy structure on the Baltic Shield, Dokl. Earth Sci., 2000, vol. 374, no. 7, pp. 1145–1148.
Pelleter, E., Cheilletz, A., Gasquet, D., Moutlaqi, A., Annich, M., El Hakour, A., Deloule, E., and Feraud, G., Hydrothermal zircons: A tool for ion microprobe U-Pb dating of gold mineralization (Tamlalt-Menhouhou gold deposit-Morocco), Chem. Geol., 2007, vol. 245, nos. 3/4, pp. 135–161.
Petrov, V.P., Metamorfizm rannego proterozoya Baltiiskogo shchita (Early Proterozoic Metamorphism of the Baltic Shield), Apatity: Kola Sci. Center, 1999.
Petrovsky, M.N., Mitrofanov, F.P., Petrovskaya, L.S., and Bayanova, T.B., New massif of Archean alkaline syenites in the Murmansk domain of the Kola Peninsula, Dokl. Earth Sci., 2009, vol. 424, no. 1, pp. 77–81.
Rukhlov, A.S. and Bell, K., Geochronology of carbonatites from the Canadian and Baltic shields, and the Canadian Cordillera: Clues to mantle evolution, Contrib. Mineral. Petrol., 2010, vol. 98, pp. 11–54.
Vetrin, V.R., Kamensky, I.L., Bayanova, T.B., Timmerman, M., Belyatsky, B.V., Levsky, L.K., and Balashov, Yu.A., Melanocratic nodules in alkaline granites of the Ponoi massif, Kola Peninsula: A clue to petrogenesis, Geochem. Int., 1999, vol. 37, no. 11, pp. 1061–1072.
Vetrin, V.R. and Kamensky, I.L., Systematics of isotopic systems (U-Pb, Sm-Nd, K-Ar, 4He-3He) in alkali granite of the Keivy Block, Kola, in XIX simpozium po geokhimii izotopov. Tez. dokl. (Abstracts of the 19th Symposium on Isotope Geochemistry), Moscow, 2010, pp. 64–67.
Vinogradov, A.N., Batieva, I.D., and Zozulya, D.R., Complex rare-metal-zirconium mineralization in the Sakharjok alkaline massif, Mineral’noe syr’e, 2000, vol. 2, issue 7, pp. 25–34.
Williams, I.S., U-Th-Pb geochronology by ion microprobe. Applications of microanalytical techniques to understanding mineralizing processes, Rev. Econ. Geol., 1998, vol. 7, pp. 1–35.
Zozulya, D.R., Bayanova, T.B., and Serov, P.N., Age and isotopic geochemical characteristics of Archean carbonatites and alkaline rocks of the Baltic Shield, Dokl. Earth Sci., 2007, vol. 415A, no. 6, pp. 874–879.
Zozulya, D.R., Lyalina, L.M., Ibi, N., and Savchenko, E.E., Ore geochemistry, zircon mineralogy, and genesis of the Sakharjok Y-Zr deposit, Geol. Ore Deposits, 2012, vol. 54, no. 2, pp. 81–98.
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Original Russian Text © V.R. Vetrin, S.G. Skublov, Yu.A. Balashov, L.M. Lyalina, N.V. Rodionov, 2014, published in Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 2014, No. 2, pp. 1–22.
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Vetrin, V.R., Skublov, S.G., Balashov, Y.A. et al. Time of formation and genesis of yttrium-zirconium mineralization in the Sakharjok massif, Kola Peninsula. Geol. Ore Deposits 56, 603–616 (2014). https://doi.org/10.1134/S107570151408011X
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DOI: https://doi.org/10.1134/S107570151408011X