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Composition, Structures, and Preparation of Smart Composite Materials Based on Polyurethane and Modified Silicon Carbide Particles with Controllable Characteristics and Kinetics of the Shape Memory Effect

  • Macromolecular Compounds and Polymeric Materials
  • Published:
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Abstract

The influence of various structural types of smart dispersion-filled polymer composite materials (DFPCMs) on such shape-memory effect (SME) parameters as the shape fixation and recovery coefficients (Rf and Rr) and SME kinetics characterized by the rate of the initial shape recovery (υr) was studied for the first time, with the polyurethane + modified silicon carbide (SiC) particles as example. The main dependences describing the relationship of the shape fixation and recovery coefficients (Rf and Rr) and of the shape recovery rate (υr) with the generalized parameter Θ, DFPCM structural type, and surface morphology of SiC particles were found. The contribution of the specific surface area of dispersed SiC particles (SBET from 3 to 45 m2 g–1) to the smart properties of the disperse systems was demonstrated for the first time.

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Funding

The study was performed within the Priority-2030 strategic academic leadership program for the Reshetnev Siberian State University.

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Authors and Affiliations

  1. Reshetnev Siberian State University of Science and Technology, 660037, Krasnoyarsk, Russia

    T. A. Shalygina

  2. Russian University of Technology MIREA (Lomonosov Institute of Fine Chemical Technologies), 119571, Moscow, Russia

    I. D. Simonov-Emelyanov

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  1. T. A. Shalygina
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  2. I. D. Simonov-Emelyanov
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Correspondence to T. A. Shalygina.

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Translated from Zhurnal Prikladnoi Khimii, No. 8, pp. 770–777, August, 2023 https://www.elibrary.ru/XGHXRV

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Shalygina, T.A., Simonov-Emelyanov, I.D. Composition, Structures, and Preparation of Smart Composite Materials Based on Polyurethane and Modified Silicon Carbide Particles with Controllable Characteristics and Kinetics of the Shape Memory Effect. Russ J Appl Chem 96, 853–860 (2023). https://doi.org/10.1134/S1070427223090045

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  • DOI: https://doi.org/10.1134/S1070427223090045

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