Abstract
Study of the carbonization of birch wood demonstrated that, under conditions of a preliminary carbonization at a temperature of 400°C, KOH favors better, compared with NaOH, development of the specific surface area (S BET ≈ 2000 m2 g−1) and microporous volume (0.6 cm3 g−1). The resulting porous carbon materials possess improved adsorption properties and are effective in separation of He(H2)-CH4 mixtures.
Similar content being viewed by others
References
Evans, M.J., Halliop, E., and MacDonald, J.A.F., Carbon, 1999, vol. 37, pp. 269–274.
Mikova, N.M., Kuznetsov, B.N., and Chesnokov, N.V., J. Siberian Federal Univ. Chem., 2009, no. 1, pp. 3–10.
Diaz-Teran, J., Nevskaia, D.N., Fierro, J.L.G., et al., Micropor. Mesopor. Mater., 2003, vol. 60, pp. 173–181.
Babel, K. and Jurewicz, K., Carbon, 2008, vol. 46, pp. 1948–1956.
Carrot, P.J.M., Ribeiro Carrot, M.M.L., and Mourao, P.A.M., J. Anal. Appl. Pyrolysis, 2006, vol. 73, pp. 120–127.
Muller-Hagedorn, M. and Bockhorn, H., J. Anal. Appl. Pyrolysis, 2007, vol. 79, pp. 136–146.
Sevilla, M. and Fuertes, A.B., Carbon, 2009, vol. 42, pp. 2281–2289.
Kiselev, A.V., Uglerodnye sorbenty i ikh primenenie v promyshlennosti (Carbon Sorbents and Their Industrial Application), Moscow: Nauka, 1983.
Kislitsin, A.N., Piroliz drevesiny: khimizm, kinetika, produkty, novye protsessy (Pyrolysis of Wood: Chemistry, Kinetics, Products, New Processes), Moscow: Lesn. Prom-st’, 1990.
Lozano-Castello, D., Calo, J.M., Cazorla-Amoros, D., and Linares-Solano, A., Carbon, 2007, vol. 45, pp. 2529–2536.
Aik Chong Lua, Ting Yang, and Jia Guo, J. Anal. Appl. Pyrolysis, 2004, vol. 72, pp. 279–287.
Trufanova, N.V., Bogdanovich, N.I., Fadeev, S.M., and Kuznetsova, L.N., II Vserossiiskaya konferentsiya “Khimiya i tekhnologiya rastitel’nykh veshchestv”, Kazan, 24–27 iyunya 2002 g. (II Al-Russia Conf. “Chemistry and Technology of Vegetable Substances,” Kazan, June 24–27, 2002), p. 153.
Losano-Gastello, D., Lillo-Rodenas, M.A., Casorla Amoros, D., and Linares-Solano, A., Carbon, 2001, vol. 39, no. 5, pp. 341–349.
Tamarkina, Yu.V., Kucherenko, V.A., and Shendrik, T.G., Russ. J. Appl. Chem., 2004, vol. 77, no. 9, pp. 1440–1443.
Luik, H., Johannes, I., Palu, V., et al., J. Anal. Appl. Pyrolysis, 2004, vol. 79, pp. 121–127.
Mamleev, V., Bourbigot, S., and Yvon, J., J. Anal. Appl. Pyrolysis, 2007, vol. 80, pp. 151–165.
Macia-Agullo, J.A., Moore, B.C., Cazorla-Amoros, D., and Linares-Solano, A., Carbon, 2004, vol. 42, pp. 1367–1370.
Chunlan, L., Shao**, X., Yixiong, G., et al., Carbon, 2005, vol. 43, no. 11, pp. 2295–2301.
Chunlan, L., Shao**, X., Mei, W., et al., Carbon, 2007, vol. 45 (Letters), pp. 206–209.
Rui-Qin Sun, Lin-Bing Sun, Yuan Chun, and Qin-Hua Xu, Carbon, 2008, vol. 46, pp. 1757–1764.
Boudou, J.P., Gerard, I., Begin, D., et al., Carbon, 2000, vol. 38, pp. 525–534.
Ming Sun and Liang Hong, Carbon, 2011, vol. 49, pp. 2173–2180.
Lopez-Garzon, F.J., Domingo-Garcia, M., Perez-Mendoza, M., et al., Langmuir, 2003, vol. 19, no. 7, pp. 2838–2844.
Abdel-Nasser A. and El-Hendawy, J. Anal. Appl. Pyrolysis, 2006, vol. 75, pp. 159–166.
Gregg, S.J. and Sing, K.S.W., Adsorption Surface Area and Porosity, London: Academic Press, 1967.
Almazan-Almazan, M.C., Perez-Mendoza, M., Domingo-Garcia, M., et al., Carbon, 2007, vol. 45, pp. 1777–1785.
Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Fundamentals of Adsorption Technique), Moscow: Khimiya, 1976.
Baklanova, O.N., Plaksin, G.V., and Drozdov, V.A., Ros. Khim. Zh., 2004, vol. 48, no. 3, pp. 89–94.
Lillo-Rodenas, M.A., Cazorla-Amoros, D., Linares-Solano, A., et al., Carbon, 2004, vol. 42, pp. 1305–1310.
Hsisheng Teng and To-Chi Weng, Micropor. Mesopor. Mater., 2001, vol. 50, pp. 53–60.
Freitas, J.C.C., Schettino, M.A.J., Cunha, A.G., et al., Carbon, 2007, vol. 45, pp. 1097–1104.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.M. Mikova, N.V. Chesnokov, I.P. Ivanov, A.M. Zhizhaev, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 10, pp. 1571–1582.
Rights and permissions
About this article
Cite this article
Mikova, N.M., Chesnokov, N.V., Ivanov, I.P. et al. Effect of methods for thermal and alkaline modification of birch wood on properties of porous carbon materials obtained. Russ J Appl Chem 86, 1526–1536 (2013). https://doi.org/10.1134/S1070427213100108
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427213100108