Abstract
The kinetics and mechanism of the electrochemical redox reaction of 3-(3,5-dimethilpirazole-1-yl)-6-R-1,2,4,5-tetrazines and their Cu(II), Co(II), and Ni(II) complexes were studied by voltammetry on glassy carbon electrodes in aqueous acetonitrile. The characteristics of electrode processes in the studied systems were determined.
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REFERENCES
Kaim, W., Coord. Chem. Rev., 2002, vol. 230, p. 127. https://doi.org/10.1016/S0010-8545(02)00044-9
Ovcharenko, V.I. and Sagdeev, R.Z., Usp. Khim., 1999, vol. 68, no. 5, pp. 381–400. https://doi.org/10.1070/RC1999v068n05ABEH000513
Audebert, P., Sadki, S., Miomandre, F., Clavier, G., Vernieres, M.C., Saoud, M., and Hapiot, P., New. J. Chem., 2004, vol. 28, pp. 387–392. https://doi.org/10.1039/b310737j
Audebert, P., Miomandre, F., Clavier, G., Verniéres, M.-C., Badré, S., and Méallet-Renault, R., Chem. Eur. J., 2005, vol. 11, pp. 5667–5673. https://doi.org/10.1002/chem.200401252
Fungo, F., Jenekbe, S.A., and Bard, A.J., Chem. Mater., 2003, vol. 15, p. 1264.
Malkov, A.E., Fomina, I.G., Sidorov, A.A., Aleksandrov, G.G., Egorov, I.M., Latosh, N.I., Chupakhin, O.N., Rusinov, G.L., Rakitin, Yu.V., Novotortsev, V.M., Ikorskii, V.N., Eremenko, I.L., and Moiseev, I.I., J. Mol. Struct., 2003, vol. 656, pp. 207–224. https://doi.org/10.1016/S0022-2860(03)00351-X
Kim, Y., Kim, E., Clavier, G., and Audebert, P., Chem. Commun., 2006, pp. 3612–3614. https://doi.org/10.1039/B608312A
Kozitsina, A.N., Shalygina, Zh.V., Dedeneva, S.S., Rusinov, G.L., Tolshchina, S.G., Verbitskii, E.V., and Brainina, Kh.Z., Izv. Akad. Nauk, Ser. Khim., 2009, no. 6, pp.1091–1097
Cherdantseva, E.V., Starichenko, D.V., Slepukhin, P.A., Ishmetova, R.I., Shvachko, Yu.N., Korolev, A.V., Rusinov, G.L., Ustinov, V.V., Matern, A.I., and Charushin, V.N., Izv. Akad. Nauk, Ser. Khim., 2010, no. 4, pp. 703–709. https://doi.org/10.1007/s11172-010-0152-x
Myers, T.W., Chavez, D.E., Hanson, S.K., Scharff, R.J., Scott, B.L., Veauthier, J.M., and Wu, R., Inorg. Chem., 2015, vol. 54, no. 16, pp. 8077–8086. doi:10.1021/acs. inorgchem.5b01313
Zozulya, A.P., Kulonometrik analiz (Coulometric Analysis), Leningrad: Khimiya, 1968.
Budnikov, G.K., Maistrenko, V.N., and Vyaselev, M.R., Osnovy sovremennogo elektrokhimicheskogo analiza (Fundamentals of Mmodern Electrochemical Analysis), Moscow: Khimiya, 2003.
Brainina Kh.Z. and Neiman, E.Ya., Tverdofaznye reaktsii v elektroanaliticheskoi khimii (Solid-Phase Reactions in Electroanalytical Chemistry), Moscow: Khimiya, 1982.
Matsuda, H. and Ayabe, J., Z. Electrochem., 1955, vol. 59, no. 6, pp. 494–503. https://doi.org/10.1002/bbpc.19550590605
Gokhshtein, Ya.P. and Gokhshtein, A.Ya., Zh. Fiz. Khim., 1960, vol. 37, no. 7, pp. 1654–1557.
Mairanovskii, S.G., J. Electroanal. Chem., 1962, vol. 4. p.166.
Mayranovskii, S.G., Stradyn’, Ya.P., and Bezuglyi, V.D., Polyarografiya v organicheskoi khimii (Polarography in Organic Chemistry), Leningrad: Khimiya, 1975.
Heyrovsky, J. and Kuta, J., Principles of Polarography, Prague: Czechoslovac Academy of Sciences, 1962.
Semerano, G. and Vianello, E., Rep. Foreign Sciences, VII Mendeleev S’ezd po obshchei i organicheskoi khimii (VII Mendeleev Congress on General and Applied Chemistry), Мoscow: 1959, pp. 49–63.
Shaidarova, L.G., Gedmina, A.V., Zhaldak, E.R., Chelnokova, I.A., and Budnikov, I.A., Uchenye Zap. Kazakh. Gos. Univ., Ser. Estestv. Nauki, 2012, vol. 154, book 3, pp. 116–126.
Coburn, M.D., Buntain, G.A., Harris, B.W., Hiskey, M.A., Lee, K.-Y., and Ott, D.G., J. Heterocycl. Chem., 1991, vol. 28, p. 2049. https://doi.org/10.1002/jhet.5570280844
Latosh, N.I., Rusinov, G.L., Ganebnykh, I.N., and Chupakhin, O.N., Zh.Org. Khim., 1999, vol. 35, no. 9, p. 1392.
Heinz G. Becker, H.G., Berger, W., and Domschke, G., Organikum: Organisch-chemisches Grundpraktikum, Berlin: Wissenschaften, 1976.
Vataman, I.I. and Chikryzova, E.G Issledovaniya po khimii koordinatsionnykh soyedinenii i fizikokhimicheskim metodam analiza (Research on the Chemistry of Coordination Compounds and Physicochemical Methods of Analysis), Kishinev: Akad. Nauk Mold. SSR, 1969, pp. 120–124.
Lingane, J.J., J. Am. Chem. Soc., 1945, vol. 67, pp. 1916–1922. https://doi.org/10.1021/ja01227a013
Funding
The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (state assignment AAAA-A-19-119012290117-6) using the equipment of the Spectroscopy and Analysis of Organic Compounds Center for Collective Use (TsKP “SAOS”).
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Dyakonova, E.V., Buldakova, L.Y., Yanchenko, M.Y. et al. Electrochemical Properties of 3-(3,5-Dimethylpyrazol-1-yl)-6-R-1,2,4,5-tetrazines and Their Complexes with Copper(II), Cobalt(II), and Nickel(II). Russ J Gen Chem 93 (Suppl 1), S277–S284 (2023). https://doi.org/10.1134/S1070363223140165
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DOI: https://doi.org/10.1134/S1070363223140165