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Morphology and Luminescent Properties of NaYF4 Microcrystalline Up-Conversion Phosphors Doped with Ytterbium(III) and Holmium(III) Ions

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Abstract

Microcrystalline phosphors NaY0.8–xYb0.2HoxF4 (x = 0–0.1) were first synthesized by the hydrothermal method. All synthesized compounds have hexagonal β-NaYF4 crystalline phase. It has been found that holmium(III) ions isomorphically replace yttrium ions. The maximum intensity of up-conversion emission in the visible region of the spectrum upon 973-nm excitation is observed for the compound NaY0.78Yb0.2Ho0.02F4.

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ACKNOWLEDGMENTS

The measurements were performed at the Research Park of Saint-Petersburg State University (Interdisciplinary Resource Centre for Nanotechnology, Centre for Optical and Laser Materials Research, Thermogravimetric and Calorimetric Research Centre, Cryogenic Department, Chemical Analysis and Materials Research Centre, Centre for X-ray Diffraction Studies, Centre for Innovative Technologies of Composite Nanomaterials, and Magnetic Resonance Research Centre).

Funding

This research was funded by Fellowship of President of Russia MD-1191.2022.1.3.

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Authors and Affiliations

  1. St. Petersburg State University, 199034, St. Petersburg, Russia

    T. S. Bulatova, A. A. Betina, V. G. Nosov, I. E. Kolesnikov, N. A. Bogachev, M. Yu. Skripkin, E. M. Khairullina & A. S. Mereshchenko

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  1. T. S. Bulatova
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  2. A. A. Betina
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  3. V. G. Nosov
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  4. I. E. Kolesnikov
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  5. N. A. Bogachev
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  6. M. Yu. Skripkin
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  7. E. M. Khairullina
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  8. A. S. Mereshchenko
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Correspondence to A. S. Mereshchenko.

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To the 300th Anniversary of St. Petersburg State University

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Bulatova, T.S., Betina, A.A., Nosov, V.G. et al. Morphology and Luminescent Properties of NaYF4 Microcrystalline Up-Conversion Phosphors Doped with Ytterbium(III) and Holmium(III) Ions. Russ J Gen Chem 93, 2058–2064 (2023). https://doi.org/10.1134/S1070363223080145

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