Abstract
An original method for the preparation of pillar[7]arene containing free hydroxyl groups was developed. Using UV-vis and NMR spectroscopy, the ability of the synthesized pillar[7]arene to interact with a polycyclic aromatic hydrocarbon, pyrene, was shown. The association constant and stoichiometry of the pillar[7]arene–pyrene complex were log Ka 4.1 and 1 : 1, respectively. The spatial structure of the resulting complex was confirmed by 2D 1H–1H NMR NOESY and DOSY spectroscopy method.
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Funding
This work was supported by the Russian Science Foundation (grant no. 22-13-00070). Registration of mass spectra was carried out at the expense of the Strategic Academic Leadership Program of the Kazan (Volga region) Federal University “Prioritet-2030.”
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To the 145th anniversary of A.E. Arbuzov
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Makhmutova, L.I., Shurpik, D.N. & Stoikov, I.I. Hydroxylated Pillar[7]arene: Synthesis and Complexing Properties with Pyrene. Russ J Gen Chem 92, 2569–2573 (2022). https://doi.org/10.1134/S1070363222120039
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DOI: https://doi.org/10.1134/S1070363222120039