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New Ni(II) and Co(II) coordination compounds construction from the ditopic 1,2,3-triazol-based aromatic heterocyclic polycarboxylic ligand

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Abstract

Mononuclear compound I ([Co(Ptia)2(H2O)4] • H2O) and 1D chain compound II ([Ni4(Cptia)4(H2O)12]∞) have been constructed from the new ditopic 1,2,3-trazol-based aromatic heterocyclic carboxylic ligand, 4-(4-carboxy-1H-1,2,3-triazol-1-yl) benzoic acid) (H2Cptia), under different pH conditions by using the hydrothermal method. Their structure was characterized by single crystal X-ray diffraction (СIF files CCDC nos. 1409531 (I) and 1409531 (II)), IR spectra, and elemental analysis. Compound I is a mononuclear compound. In II, two sets of parallel arrangement 1D chains orient in different directions. The results of their magnetic measurements display the antiferromagnetic interaction exists among the paramagnetic ions.

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Authors and Affiliations

  1. Department of Applied Chemistry, Tian** University of Technology, Tian**, 300384, P.R. China

    Z. Zhou, W. Q. Zhang, R. R. Bian, C. X. Lan & S. Y. Liao

  2. Department of Chemistry, Nankai University, Tian**, 300071, P.R. China

    W. Gu & X. Liu

  3. Collaborative Innovation Center of Chemical Science and Engineering, Tian**, 300071, P.R. China

    W. Gu & X. Liu

Authors
  1. Z. Zhou
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  2. W. Q. Zhang
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  3. R. R. Bian
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  4. C. X. Lan
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  5. W. Gu
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  6. X. Liu
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  7. S. Y. Liao
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Correspondence to X. Liu or S. Y. Liao.

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Zhou, Z., Zhang, W.Q., Bian, R.R. et al. New Ni(II) and Co(II) coordination compounds construction from the ditopic 1,2,3-triazol-based aromatic heterocyclic polycarboxylic ligand. Russ J Coord Chem 42, 385–391 (2016). https://doi.org/10.1134/S1070328416060099

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  • DOI: https://doi.org/10.1134/S1070328416060099

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