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Synthesis, structure, and characterization of a 1D monocopper substituted Dawson-type arsenotungstate (H2En)0.5[Cu(En)2]0.5{[Cu(En)2(H2O)]2[Cu(En)2] (α1-As2W17CuO61)} · 8H2O

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Abstract

A new 1D organic-inorganic hybrid monocopper substituted Dawson-type arsenotungstate (H2En)0.5[Cu(En)2]0.5{[Cu(En)2(H2O)]2[Cu(En)2](α1-As2W17CuO61)} · 8H2O (I) has been hydrothermally synthesized by the reaction of Na8[A-α-HAsW9O34] · 11H2O, CuCl2 · 2H2O, YCl3, with enthylenediamine (En) and characterized by elemental analyses, IR spectra, UV spectra, powder X-ray diffraction, thermogravimetric analysis, as well as single-crystal X-ray diffraction. Single-crystal structural analysis shows that I displays an interesting 1D chain constructed from [α1-As2W17CuO61]8− subunits by means of common oxygen atoms and [Cu(En)2]2+ bridges. It should be noted that the structural transformation of the trivacant Keggin polyoxoanion [A-α-AsW9O34]9− to the monovacant Dawson [α-As2W17O61]10− polyoxoanion was observed. The TG curve of I exhibits three stages of weight loss.

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Authors and Affiliations

  1. Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China

    X. R. Pei, Y. Y. Li, D. Y. Shi, J. Luo, L. J. Chen & J. W. Zhao

  2. Department of Chemistry, Zhengzhou Normal University, Zhengzhou, Henan, 450044, P.R. China

    X. R. Pei

  3. Basic Experiment Teaching Center, Henan University, Kaifeng, Henan, 475004, P.R. China

    L. J. Chen

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  1. X. R. Pei
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  2. Y. Y. Li
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  3. D. Y. Shi
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  4. J. Luo
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  5. L. J. Chen
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  6. J. W. Zhao
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Correspondence to J. W. Zhao.

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Pei, X.R., Li, Y.Y., Shi, D.Y. et al. Synthesis, structure, and characterization of a 1D monocopper substituted Dawson-type arsenotungstate (H2En)0.5[Cu(En)2]0.5{[Cu(En)2(H2O)]2[Cu(En)2] (α1-As2W17CuO61)} · 8H2O. Russ J Coord Chem 38, 99–105 (2012). https://doi.org/10.1134/S1070328412010083

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  • DOI: https://doi.org/10.1134/S1070328412010083

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