Abstract
A new organometallic-inorganic hybrid compound {[Mn(L)2]2[PMo12O40][NO3] · 4CH3OH · 3H2O} n (I), where L is 1,4-bis(4-imidazolyl)-2,3-diaza-1,3-butadiene) was synthesized in situ from [PMo12O40]3−, Mn2+ and L reaction in an H2O-DMSO-CH3OH mixture at room temperature, and the product was structurally characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound I is constructed from alternating layers of the metal-Schiff-base cation and Keggin anions based on electrostatic forces and hydrogen bond interactions.
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Wei, M.L., Zhuang, P.F., Sun, R.P. et al. A new supramolecular compound based on Mn(II)-Schiff-base and Keggin-type [PMo12O40]3− . Russ J Coord Chem 37, 30–35 (2011). https://doi.org/10.1134/S1070328411010167
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DOI: https://doi.org/10.1134/S1070328411010167