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Cubic and Tetragonal Modifications in BaTiO3 Ceramic Samples: X-Ray Diffraction Analysis by the Rietveld Method

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Abstract

The structures of ground ceramic BaTiO3 samples, prepared by solid-phase synthesis at maximum sintering temperatures of 1350, 1400, 1410, and 1500°C, have been analyzed by the Rietveld method. It is shown that, along with the tetragonal phase, the samples contain the cubic BaTiO3 phase with an effective content of about 30 vol %. The cubic phase was observed as a thin layer on the surface of ceramics grains with tetragonal structure. The efficiency of preliminary analysis of specific ranges of X-ray diffraction patterns containing strong peaks is demonstrated.

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REFERENCES

  1. Barium Titanate: Proc. Seminar on Ferroelectricity, FIAN, 1970, Ed. by N. V. Belov (Nauka, Moscow, 1973).

    Google Scholar 

  2. M. E. Lines and A. M. Glass, Principles and Applications of Ferroelectrics and Related Materials (Oxford Univ. Press, New York, 1977).

    Google Scholar 

  3. G. H. Haertling, J. Am. Ceram. Soc. 82 (4), 797 (1999).

    Article  Google Scholar 

  4. B. A. Rotenberg, Ceramic Capacitor Insulators (OAO NII “Girikond,” St. Petersburg, 2000) [in Russian].

  5. K. Kinoshita and A. Yamaji, J. Appl. Phys. 47 (1), 371 (1976).

    Article  ADS  Google Scholar 

  6. G. Arlt, D. Hennings, and G. De With, J. Appl. Phys. 58 (4), 1619 (1985).

    Article  ADS  Google Scholar 

  7. T. Takeuchi, R. Ado, T. Asai, et al., J. Am. Ceram. Soc. 77 (6), 1665 (1994).

    Article  Google Scholar 

  8. C. Miot, C. Proust, and E. Husson, J. Eur. Ceram. Soc. 15, 1163 (1995).

    Article  Google Scholar 

  9. M. H. Frey, Z. Xu, P. Han, and D. A. Payne, Ferroelectrics 206–207, 337 (1998).

    Article  Google Scholar 

  10. M. P. Mc Neal, S.-J. Jang, and R. E. Newnham, J. Appl. Phys. 83 (6), 3288 (1998).

    Article  ADS  Google Scholar 

  11. J.-K. Lee, K.-S. Hong, and J.-W. Jang, J. Am. Ceram. Soc. 84 (9), 2001 (2001).

    Article  Google Scholar 

  12. R. Chen, X. Wang, L. Li, and Z. Gui, Key Eng. Mater. 224–226, 37 (2002).

    Article  Google Scholar 

  13. A. V. Polotai, A. V. Ragulya, and C. A. Randall, Ferroelectrics 288, 93 (2003).

    Article  Google Scholar 

  14. H. T. Kim and Y. H. Han, Ceram. Int. 30, 1719 (2004).

    Article  Google Scholar 

  15. L. Curecheriu, M. T. Buscaglia, V. Buscaglia, et al., Appl. Phys. Lett. 97, 242909 (2010).

    Article  ADS  Google Scholar 

  16. Y.-K. Choi, T. Hoshina, T. Takeda, et al., Appl. Phys. Lett. 97 (21), 212907 (2010).

    Article  ADS  Google Scholar 

  17. J. Petzelt, Ferroelectrics 400, 117 (2010).

    Article  Google Scholar 

  18. I. Fujii, M. Ugorek, and S. T. Mc Kinstry, J. Appl. Phys. 107, 104116 (2010).

    Article  ADS  Google Scholar 

  19. T. Hoshina, J. Ceram. Soc. Jpn. 121 (2), 156 (2013).

    Article  Google Scholar 

  20. Y. Li, G. Dong, B. Zhu, et al., Adv. Mater. Res. 750–752, 506 (2013).

    Google Scholar 

  21. M. K. Rahman, M. F. Hossain, K. M. Shorowordi, and M. A. Matin, Appl. Mech. Mater. 860, 129 (2016).

    Article  Google Scholar 

  22. D. K. Sandi, A. Supriyanto, A. Jamaluddin, and Y. Iriani, IOP Conf. Ser.: Mater. Sci. Eng. 107, 012069 (2006).

  23. N. Sareecha, W. A. Shah, M. Anis-ur-Rehman, et al., Solid State Ionics 303, 16 (2017).

    Article  Google Scholar 

  24. D. Lu, X. Gao, and Y. Fu, Topics Chem. Mater. Eng. 1 (1), 79 (2018).

    Google Scholar 

  25. S. Aoyagi, Y. Kuroiwa, A. Sawada, et al., J. Phys. Soc. Jpn. 71 (5), 1218 (2002).

    Article  ADS  Google Scholar 

  26. Y.-I. Kim, J. K. Jung, and K.-S. Ryu, Mater. Res. Bull. 39, 1045 (2004).

    Article  Google Scholar 

  27. M. Yashima, T. Hoshina, D. Ishimura, et al., J. Appl. Phys. 98 (8), 014313 (2005).

    Article  ADS  Google Scholar 

  28. M. B. Smith, K. Page, T. Siegrist, et al., J. Am. Chem. Soc. 130, 6955 (2008).

    Article  Google Scholar 

  29. C. J. **ao, C. Q. **, and X. H. Wang, Mater. Chem. Phys. 111, 209 (2008).

    Article  Google Scholar 

  30. L. M. Wang, X. Y. Deng, J. B. Li, et al., Mater. Res. Innovations 17 (1), 190 (2013).

    Article  Google Scholar 

  31. T. Maiti, R. Guo, and A. S. Bhalla, J. Am. Ceram. Soc. 91 (6), 1769 (2008).

    Article  Google Scholar 

  32. Y. Yang, Y. Zhou, J. Ren, et al., J. Am. Ceram. Soc. 101 (6), 2594 (2018).

    Article  Google Scholar 

  33. W. Kraus and G. Nolze, J. Appl. Crystallogr. 29, 301 (1996).

    Article  Google Scholar 

  34. J. Rodriguez-Carvajal, FullProf Suite Program (1.0) Version Feb.2007.

  35. V. P. Sirotinkin, A. A. Bush, K. E. Kamentsev, et al., Ross. Tekhnol. Zh. 5 (1), 15 (2017).

    Google Scholar 

  36. R. H. Buttner and E. N. Malsen, Acta Crystallogr. B 48, 764 (1992).

    Article  Google Scholar 

  37. S. Krumm, Mater. Sci. Forum. 228–231, 183 (1996).

    Article  Google Scholar 

  38. R. Delhez, Th. H. De Keijser, and E. J. Mittemeijer, Surf. Eng. 3(4), 331 (1987).

    Article  Google Scholar 

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Authors and Affiliations

  1. Russian Technological University (MIREA), 119454, Moscow, Russia

    A. A. Bush

  2. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

    V. P. Sirotinkin

  3. Moscow State University, 119991, Moscow, Russia

    S. A. Ivanov

Authors
  1. A. A. Bush
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  2. V. P. Sirotinkin
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  3. S. A. Ivanov
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Correspondence to V. P. Sirotinkin.

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Translated by Yu. Sin’kov

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Bush, A.A., Sirotinkin, V.P. & Ivanov, S.A. Cubic and Tetragonal Modifications in BaTiO3 Ceramic Samples: X-Ray Diffraction Analysis by the Rietveld Method. Crystallogr. Rep. 65, 1025–1032 (2020). https://doi.org/10.1134/S106377452005003X

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  • DOI: https://doi.org/10.1134/S106377452005003X

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