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Crystal and molecular structures of trifluoromethyl derivatives of fullerene C86, C86(CF3)16 and C86(CF3)18

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Abstract

Trifluoromethyl derivatives of C86 were obtained by the reaction of a mixture of higher fullerenes with trifluoromethyl iodide, followed by the HPLC separation of the products. The crystal and molecular structures of C86(CF3)16 (two isomers) and C86(CF3)18 were determined by single-crystal X-ray diffraction using synchrotron radiation. All compounds studied are derivatives of the cage isomer of C86 no. 17 (C 2).

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Authors and Affiliations

  1. Chemistry Department, Moscow State University, Moscow, 119991, Russia

    S. I. Troyanov & N. B. Tamm

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  1. S. I. Troyanov
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  2. N. B. Tamm
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Correspondence to S. I. Troyanov.

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Original Russian Text © S.I. Troyanov, N.B. Tamm, 2009, published in Kristallografiya, 2009, Vol. 54, No. 4, pp. 637–641.

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Troyanov, S.I., Tamm, N.B. Crystal and molecular structures of trifluoromethyl derivatives of fullerene C86, C86(CF3)16 and C86(CF3)18 . Crystallogr. Rep. 54, 598–602 (2009). https://doi.org/10.1134/S1063774509040099

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  • DOI: https://doi.org/10.1134/S1063774509040099

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