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New Markers for Determining the Chemical and Isomeric Composition of Carotenoids by Raman Spectroscopy

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Abstract

The experimental and calculated on the basis of density functional theory Raman spectra of plant and bacterial carotenoids (neurosporene, spheroidene, lycopene, spirilloxanthin, β-carotene, lutein, ζ-carotene, α-carotene, and γ-carotene) are analyzed. A number of characteristic features in the Raman spectra of carotenoids are described for the first time, which make it possible to determine the structure of the end groups of molecules and to distinguish their isomers.

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ACKNOWLEDGMENTS

The authors express their gratitude to the Joint Supercomputer Center, Russian Academy of Sciences, for providing computing resources. The authors thank Professor S. Takaichi from Nippon Medical School (Japan) for providing samples of Rhodobacter sphaeroides G1C.

Funding

This study was carried out with funds from a grant from the Ministry of Science and Higher Education of the Russian Federation for large-scale scientific projects in priority areas of scientific and technological development (grant identifier 075-15-2020-774).

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Authors and Affiliations

  1. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, Russia

    D. D. Vasimov, S. V. Gudkov, D. V. Yanykin & V. S. Novikov

  2. Pushchino Science Center for Biological Research, Russian Academy of Sciences, Pushchino, Moscow oblast, Russia

    A. A. Ashikhmin, M. A. Bolshakov & D. V. Yanykin

  3. Federal Scientific Agroengineering Center VIM, Moscow, Russia

    M. N. Moskovsky & S. V. Gudkov

Authors
  1. D. D. Vasimov
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  2. A. A. Ashikhmin
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  3. M. A. Bolshakov
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  4. M. N. Moskovsky
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  5. S. V. Gudkov
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  6. D. V. Yanykin
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  7. V. S. Novikov
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Correspondence to V. S. Novikov.

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Translated by T. Sokolova

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Vasimov, D.D., Ashikhmin, A.A., Bolshakov, M.A. et al. New Markers for Determining the Chemical and Isomeric Composition of Carotenoids by Raman Spectroscopy. Dokl. Phys. 68, 359–365 (2023). https://doi.org/10.1134/S1028335823110071

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