Abstract
Poly(methacryloylamino galactose) is synthesized, and the hydrodynamic characteristics of its macromolecules in aqueous solutions are studied by translational diffusion, velocity sedimentation, and viscometry. Experiments are performed using polymer fractions. Polydispersity of the systems under study is estimated. The system of scaling relations is obtained in a wide molecular mass range. The equilibrium rigidity of poly(methacryloylamino galactose) chains is calculated from the translational and rotational friction data.
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REFERENCES
S. G. Spain, M. Z. Gibson, and N. R. Cameron, J. Polym.Sci., Polym.Chem. 45, 2059 (2007).
B. Voit, and D. Appelhans, Macromol. Chem. Phys. 211, 727 (2010).
E. F. Panarin, A. T. Belokhvostova, N. P. Ivanova, and L. S. Potapenkova, Immunologiya, No. 2, 26 (1999).
E. F. Panarin, N. P. Ivanova, A. T. Belokhvostova, and L. S. Potapenkova, Khim. Farmatsevt. Zh. 36 (4), 19 (2002).
Z. Zhao, A. Ukidve, J. Kim, and S. Mitragotri, Cell 181, 151 (2020).
F. Chen and G. Huang, Eur. J. Med. Chem. 182, 111612 (2019).
T. Minko, Adv. Drug Deliv. Rev. 56, 491 (2004).
J. Klein and D. Herzog, Makromol. Chem. 188 (6), 1217 (1987).
G. M. Pavlov, E. V. Korneeva, N. A. Mikhailova, N. P. Ivanova, and E. F. Panarin, Polym. Sci., Vysokomol. Soedin., Ser. A 35 (10), 1646 (1993).
V. A. Korzhikov, S. Diederichs, O. V. Nazarova, E. G. Vlakh, C. Kasper, E. F. Panarin, and T. B. Tennikova, J. Appl. Polym. Sci. 108 (4), 2386 (2008).
V. N. Tsvetkov, V. E. Eskin, and S. Ya. Frenkel, Structure of Macromolecules in Solution (England Nat. Lend. Library Sci. and Technol., Boston, 1971).
V. P. Lavrenko and P. N. Lavrenko, Prog. Colloid Polym. Sci. 131, 23 (2006).
V. N. Tsvetkov, Rigid–Chain Polymers: Hydrodynamic and Optical Properties in Solution (Plenum Press, New York, 1989).
P. Schuck, Biophys. J. 78 (3), 1606 (2000).
P. Schuck, SEDFIT, https://sedfitsedphat.nibib.nih.gov/software/default.aspx Accessed July 15, 2021.
G. M. Pavlov, O. V. Okatova, A. V. Mikhailova, N. N. Ulyanova, I. I. Gavrilova, and E. F. Panarin, Macromol. Biosci. 10 (7), 790 (2010).
G. M. Pavlov, O. V. Okatova, A. S. Gubarev, I. I. Gavrilova, and E. F. Panarin, Macromolecules 47 (8), 2748 (2014).
G. M. Pavlov, I. Y. Perevyazko, O. V. Okatova, and U. S. Schubert, Methods 54 (1), 124 (2011).
G. Pavlov, Analytical Ultracentrifugation: Instrumentation, Software, and Applications, Ed. by S. Uchiyama, W.F. A. F. Arisaka, W. Stafford, and T. Laue (Springer Link, Tokyo, 2016), p. 269.
G. Pavlov, S. Finet, K. Tatarenko, E. Korneeva, and C. Ebel, Eur. Biophys. J. 32, 437 (2003).
G. M. Pavlov and S. Ya. Frenkel, Vysokomolek. Soed., Ser. B 24, 178 (1982).
G. M. Pavlov and S. Ya. Frenkel, Prog. Colloid Polym. Sci. 99, 109 (1995).
G. M. Pavlov, E. V. Korneeva, K. Zhumel, S. E. Kharding, A. Yu. Ershov, I. I. Gavrilova, and E. F. Panarin, Zh. Prikl. Khim. 73 (6) 992 (2000).
V. N. Tsvetkov, P. N. Lavrenko, and S. V. Bushin, Usp. Khim. 51 (10), 1698 (1982).
M. Grube, G. Cinar, U. S. Schubert, and I. Nischang, Polymers, 12 (2), 277 (2020).
G. M. Pavlov and S. Ya. Frenkel, Prog. Colloid Polym. Sci. 99, 101 (1995).
G. Gray, V. Bloomfield, and J. Hearst, J. Chem. Phys. 46 (4), 1493 (1967).
G. M. Pavlov, Analytical Ultracentrifugation VI, Ed. by W. Borchard and A. Straatmann (Springer, Berlin, Heidelberg, 2002), Vol. 119, p. 149.
G. M. Pavlov, E. F. Panarin, E. V. Korneeva, C. V. Kurochkin, V. E. Baikov, and V. N. Ushakova, Makromol. Chem. 191 (12), 2889 (1990).
O. B. Ptitsyn and Yu. E. Eizner, Zh. Tekh. Fiz. 29, 1105 (1959).
B. H. Zimm, Macromolecules 13, 592 (1980).
J. M. Garcia Bernal, M. M. Tirado, J. Freire, and J. G. de la Torre, Macromolecules 24 (2), 593 (1991).
Y. Oono, Adv. Chem. Phys. 61, 301 (1985).
J. M. Garcia Bernal, M. M. Tirado, J. J. Freire, and J. G. de la Torre, Macromolecules 24 (2), 593 (1991).
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Dommes, O.A., Okatova, O.V., Zhuravskaya, O.N. et al. Molecular Hydrodynamics and Conformations of Poly(methacryloylamino galactose) in Aqueous Solutions. Polym. Sci. Ser. A 64, 255–260 (2022). https://doi.org/10.1134/S0965545X22030038
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DOI: https://doi.org/10.1134/S0965545X22030038