Log in

Molecular Hydrodynamics and Conformations of Poly(methacryloylamino galactose) in Aqueous Solutions

  • SOLUTIONS
  • Published:
Polymer Science, Series A Aims and scope Submit manuscript

Abstract

Poly(methacryloylamino galactose) is synthesized, and the hydrodynamic characteristics of its macromolecules in aqueous solutions are studied by translational diffusion, velocity sedimentation, and viscometry. Experiments are performed using polymer fractions. Polydispersity of the systems under study is estimated. The system of scaling relations is obtained in a wide molecular mass range. The equilibrium rigidity of poly(methacryloylamino galactose) chains is calculated from the translational and rotational friction data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. S. G. Spain, M. Z. Gibson, and N. R. Cameron, J. Polym.Sci., Polym.Chem. 45, 2059 (2007).

    Article  CAS  Google Scholar 

  2. B. Voit, and D. Appelhans, Macromol. Chem. Phys. 211, 727 (2010).

    Article  CAS  Google Scholar 

  3. E. F. Panarin, A. T. Belokhvostova, N. P. Ivanova, and L. S. Potapenkova, Immunologiya, No. 2, 26 (1999).

  4. E. F. Panarin, N. P. Ivanova, A. T. Belokhvostova, and L. S. Potapenkova, Khim. Farmatsevt. Zh. 36 (4), 19 (2002).

    Google Scholar 

  5. Z. Zhao, A. Ukidve, J. Kim, and S. Mitragotri, Cell 181, 151 (2020).

    Article  CAS  Google Scholar 

  6. F. Chen and G. Huang, Eur. J. Med. Chem. 182, 111612 (2019).

  7. T. Minko, Adv. Drug Deliv. Rev. 56, 491 (2004).

    Article  CAS  Google Scholar 

  8. J. Klein and D. Herzog, Makromol. Chem. 188 (6), 1217 (1987).

    Article  CAS  Google Scholar 

  9. G. M. Pavlov, E. V. Korneeva, N. A. Mikhailova, N. P. Ivanova, and E. F. Panarin, Polym. Sci., Vysokomol. Soedin., Ser. A 35 (10), 1646 (1993).

    Google Scholar 

  10. V. A. Korzhikov, S. Diederichs, O. V. Nazarova, E. G. Vlakh, C. Kasper, E. F. Panarin, and T. B. Tennikova, J. Appl. Polym. Sci. 108 (4), 2386 (2008).

    Article  CAS  Google Scholar 

  11. V. N. Tsvetkov, V. E. Eskin, and S. Ya. Frenkel, Structure of Macromolecules in Solution (England Nat. Lend. Library Sci. and Technol., Boston, 1971).

    Google Scholar 

  12. V. P. Lavrenko and P. N. Lavrenko, Prog. Colloid Polym. Sci. 131, 23 (2006).

    Article  CAS  Google Scholar 

  13. V. N. Tsvetkov, Rigid–Chain Polymers: Hydrodynamic and Optical Properties in Solution (Plenum Press, New York, 1989).

    Google Scholar 

  14. P. Schuck, Biophys. J. 78 (3), 1606 (2000).

    Article  CAS  Google Scholar 

  15. P. Schuck, SEDFIT, https://sedfitsedphat.nibib.nih.gov/software/default.aspx Accessed July 15, 2021.

  16. G. M. Pavlov, O. V. Okatova, A. V. Mikhailova, N. N. Ulyanova, I. I. Gavrilova, and E. F. Panarin, Macromol. Biosci. 10 (7), 790 (2010).

    Article  CAS  Google Scholar 

  17. G. M. Pavlov, O. V. Okatova, A. S. Gubarev, I. I. Gavrilova, and E. F. Panarin, Macromolecules 47 (8), 2748 (2014).

    Article  CAS  Google Scholar 

  18. G. M. Pavlov, I. Y. Perevyazko, O. V. Okatova, and U. S. Schubert, Methods 54 (1), 124 (2011).

    Article  CAS  Google Scholar 

  19. G. Pavlov, Analytical Ultracentrifugation: Instrumentation, Software, and Applications, Ed. by S. Uchiyama, W.F. A. F. Arisaka, W. Stafford, and T. Laue (Springer Link, Tokyo, 2016), p. 269.

    Google Scholar 

  20. G. Pavlov, S. Finet, K. Tatarenko, E. Korneeva, and C. Ebel, Eur. Biophys. J. 32, 437 (2003).

    Article  CAS  Google Scholar 

  21. G. M. Pavlov and S. Ya. Frenkel, Vysokomolek. Soed., Ser. B 24, 178 (1982).

    CAS  Google Scholar 

  22. G. M. Pavlov and S. Ya. Frenkel, Prog. Colloid Polym. Sci. 99, 109 (1995).

    Article  CAS  Google Scholar 

  23. G. M. Pavlov, E. V. Korneeva, K. Zhumel, S. E. Kharding, A. Yu. Ershov, I. I. Gavrilova, and E. F. Panarin, Zh. Prikl. Khim. 73 (6) 992 (2000).

    CAS  Google Scholar 

  24. V. N. Tsvetkov, P. N. Lavrenko, and S. V. Bushin, Usp. Khim. 51 (10), 1698 (1982).

    Article  CAS  Google Scholar 

  25. M. Grube, G. Cinar, U. S. Schubert, and I. Nischang, Polymers, 12 (2), 277 (2020).

    Article  CAS  Google Scholar 

  26. G. M. Pavlov and S. Ya. Frenkel, Prog. Colloid Polym. Sci. 99, 101 (1995).

    Article  CAS  Google Scholar 

  27. G. Gray, V. Bloomfield, and J. Hearst, J. Chem. Phys. 46 (4), 1493 (1967).

    Article  CAS  Google Scholar 

  28. G. M. Pavlov, Analytical Ultracentrifugation VI, Ed. by W. Borchard and A. Straatmann (Springer, Berlin, Heidelberg, 2002), Vol. 119, p. 149.

    Google Scholar 

  29. G. M. Pavlov, E. F. Panarin, E. V. Korneeva, C. V. Kurochkin, V. E. Baikov, and V. N. Ushakova, Makromol. Chem. 191 (12), 2889 (1990).

    Article  CAS  Google Scholar 

  30. O. B. Ptitsyn and Yu. E. Eizner, Zh. Tekh. Fiz. 29, 1105 (1959).

  31. B. H. Zimm, Macromolecules 13, 592 (1980).

    Article  CAS  Google Scholar 

  32. J. M. Garcia Bernal, M. M. Tirado, J. Freire, and J. G. de la Torre, Macromolecules 24 (2), 593 (1991).

    Article  CAS  Google Scholar 

  33. Y. Oono, Adv. Chem. Phys. 61, 301 (1985).

    CAS  Google Scholar 

  34. J. M. Garcia Bernal, M. M. Tirado, J. J. Freire, and J. G. de la Torre, Macromolecules 24 (2), 593 (1991).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to G. M. Pavlov.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by T. Soboleva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dommes, O.A., Okatova, O.V., Zhuravskaya, O.N. et al. Molecular Hydrodynamics and Conformations of Poly(methacryloylamino galactose) in Aqueous Solutions. Polym. Sci. Ser. A 64, 255–260 (2022). https://doi.org/10.1134/S0965545X22030038

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X22030038

Navigation