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Preparation of the Au/TiO2 Catalyst for the Oxidation of 2-Phenylethyl Alcohol using a Cacumen Platycladi Extract as a Reducing Agent

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Abstract

A Supported gold catalyst was prepared by reduction of HAuCl4 with the Cacumen Platycladi extract. This catalyst was then used for oxidation of 2-phenylethyl alcohol in a model reaction. Our study evaluated the effect of various preparation conditions, including the Au loading ratio and calcination temperature. Additionally, we explored the influence of the reaction temperature and reaction time on the catalytic performance of a Au/TiO2 catalyst. Our experimental findings revealed notable results for the Au/TiO2 catalyst characterized by the Au loading of 1.3 wt % and calcinated at 400°C. Under specific reaction conditions (0.3 g catalyst, 220°C, 3.0 MPa, 2.5 h), the conversion of 2-phenylethyl alcohol reached 45.3 and a 59.6% selectivity and a 27.0% yield of the target product (phenylacetaldehyde). In addition, catalytic performance remained stable after 8 repeated uses.

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REFERENCES

  1. Li, X., Tieman, D., Alseekh, S., Fernie, A.R., and Klee, H.J., Plant J., 2023, vol. 115, no. 4, pp. 1134‒1150. https://doi.org/10.1111/tpj.16310

    Article  CAS  PubMed  Google Scholar 

  2. Klee, H.J. and Tieman, D.M., Nat. Rev. Genet., 2018, vol. 19, no. 6, pp. 347‒356. https://doi.org/10.1038/s41576-018-0002-5

    Article  CAS  PubMed  Google Scholar 

  3. Pavillard, E.R. and Wright, E.A., Nature, 1957, vol. 180, no. 1, pp. 916‒917. https://doi.org/10.1038/180916b0

    Article  CAS  PubMed  Google Scholar 

  4. Tóth, M., Bozsik, A., Szentkirályi, F., Letardi, A., Tabilio, M.R., Verdinelli, M., Zandigiacomo, P., Jekisa, J., and Szarukán, I., Eur. J. Entomol., 2006, vol. 103, no. 1, pp. 267‒271. https://doi.org/10.14411/eje.2006.033

    Article  Google Scholar 

  5. Katritzky, A.R., Luxem, F.J., and Siskin, M., Energy Fuels, 1990, vol. 4, no. 5, pp. 525‒531. https://doi.org/10.1021/ef00023a021

    Article  CAS  Google Scholar 

  6. Le Guenic, S., Ceballos, C., and Len, C., Catal. Lett., 2015, vol. 145, no. 10, pp. 1851‒1855. https://doi.org/10.1007/s10562-015-1606-4

    Article  CAS  Google Scholar 

  7. Zhou, C., Guo, Z., Dai, Y., Jia, X., Yuc, H., and Yang, Y., Appl. Catal. B: Environ., 2016, vol. 181, no. 1, pp. 118‒126. https://doi.org/10.1016/j.apcatb.2015.07.048

    Article  CAS  Google Scholar 

  8. Sun, J., Han, Y., Fu, H., Qu, X., Xu, Z., and Zheng, S., Chem. Eng. J., 2017, vol. 313, no. 1, pp. 1‒9. https://doi.org/10.1016/j.cej.2016.12.024

    Article  CAS  Google Scholar 

  9. Yuan, S., Lv, X., Zhang, Y., Wu, Y., Mao, C., Zhou, Y., Chen, W., and Wang, Y., J. Taiwan Inst. Chem. Eng., 2019, vol. 103, no. 1, pp. 138‒148. https://doi.org/10.1016/j.jtice.2019.06.021

    Article  CAS  Google Scholar 

  10. Choudhary, V.R., Dhar, A., Jana, P., Jha, R., and Uphade, B.S., Green Chem., 2005, vol. 7, no. 11, pp. 768‒770. https://doi.org/10.1039/b509003b

    Article  CAS  Google Scholar 

  11. Zhu, J., Wang, P.C., and Lu, M., Appl. Catal. A: Gen., 2014, vol. 477, no. 1, pp.125‒131. https://doi.org/10.1016/j.apcata.2014.03.013

    Article  CAS  Google Scholar 

  12. Zhan, G., Huang, J., Du, M., Sun, D., Abdul-Rauf, I., Lin, W., Hong, Y., and Li, Q., Chem. Eng. J., 2012, vol. 187, no. 1, pp. 232‒238. https://doi.org/10.1016/j.cej.2012.01.051

  13. Mahiuddin, M. and Ochiai, B., Mater. Today Sustain., 2023, vol. 22, no. 1, ID 100383. https://doi.org/10.1016/j.mtsust.2023.100383

  14. Arun, S.B., Karthik, B.M., Yatish, K.V., Prashanth, K.N., and Balakrishna, G.R., Energy, 2023, vol. 274, no. 1, ID 127345. https://doi.org/10.1016/j.energy.2023.127345

  15. Zelekew, O.A., Haitosa, H.H., Chen, X., and Wu, Y., Adv. Colloid Interface Sci., 2023, vol. 317, no. 1, ID 102931. https://doi.org/10.1016/j.cis.2023.102931

  16. Sun, M., Zhou, Y., Yang, M., and Wang, J., J. Clean. Prod., 2024, vol. 448, ID 141302. https://doi.org/10.1016/j.jclepro.2024.141302

  17. Zheng, B., Kong, T., **g, X., Odoom-Wubah, T., Li, X., Sun, D., Lu, F., Zheng, Y., Huang, J., and Li, Q., J. Colloid Interface Sci., 2013, vol. 396, pp. 138‒145. https://doi.org/10.1016/j.jcis.2013.01.021

    Article  CAS  PubMed  Google Scholar 

  18. Choudhary, V.R. and Dumbre, D.K., Catal. Commun., 2011, vol. 13, no. 1, pp. 82‒86. https://doi.org/10.1016/j.catcom.2011.07.001

    Article  CAS  Google Scholar 

  19. Çelik, D., Bayraktar, E., and Mehmetoğlu, Ü., Biochem. Eng. J., 2004, vol. 17, no. 1, pp. 5‒13. https://doi.org/10.1016/s1369-703x(03)00119-0

    Article  Google Scholar 

  20. Costa, V.V., da Silva Rocha, K.A., Kozhevnikov, I.V., and Gusevskaya, E.V., Appl. Catal. A: Gen., 2010, vol. 383, nos. 1‒2, pp. 217‒220. https://doi.org/10.1016/j.apcata.2010.06.005

    Article  CAS  Google Scholar 

  21. Mei, X., Liu, H., Wu, H., Wu, W., Zheng, B., Zhang, K., Xu, C., Xu, J., He, M., and Han, B., ChemCatChem, 2022, vol. 14, no. 19, pp. 1‒6. https://doi.org/10.1002/cctc.202200554

    Article  CAS  Google Scholar 

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Funding

This research was supported by the science and technology projects fund of Yangzhou City (grants YZ2022081) and Jiangsu Province Industry-Academia-Research Cooperation Project (BY20221405).

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Authors and Affiliations

  1. Yangzhou Polytechnic Institute, 225127, Yangzhou, China

    Jiali **ao, Longsheng Zhou, Dangqin ** & Hui Zhou

  2. Jiangsu Tianyu Group, 225265, Yangzhou, China

    Jiali **ao

  3. SUMEC New Material Technology Development Co. Ltd., 225009, Yangzhou, China

    Dongfan Liu

  4. Putian University, 351100, Fujian, China

    Bingyun Zheng

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  1. Jiali **ao
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  2. Longsheng Zhou
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  3. Dangqin **
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Correspondence to Jiali **ao.

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**ao, J., Zhou, L., **, D. et al. Preparation of the Au/TiO2 Catalyst for the Oxidation of 2-Phenylethyl Alcohol using a Cacumen Platycladi Extract as a Reducing Agent. Pet. Chem. 64, 322–329 (2024). https://doi.org/10.1134/S0965544124030125

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