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Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products. Physicochemical Foundations of Crystallization of Binary Mixtures of cis- and trans-Perfluorodecalin and Perfluorobutylcyclohexane

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Abstract—

Physical–chemical data on the liquid–solid phase transitions in the binary systems trans-perfluorodecalin (trans-PFD)–cis-perfluorodecalin (cis-PFD), trans-PFD–perfluorobutylcyclohexane (BCH), and cis-PFD–BCH are obtained. All three systems are characterized by the presence of a temperature extremum on the fusibility curve. For the trans-PFD–BCH system, the liquidus line can be described by the equation for simple eutectic systems with the assumed activity coefficient \(\gamma _{i}^{l}\) = 1, which indicates that the behavior of the system is close to ideal. The process of bulk crystallization is considered using the example of a cis‑PFD–BCH mixture. It is demonstrated that from cis-PFD–BCH mixtures with an initial content xcis-PFD = 0.7348 and 0.6447 mol. fr., cis-PFD can be isolated with a purity of more than 0.99 mol. fr. in three crystallization cycles.

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ACKNOWLEDGMENTS

The NMR analysis was performed using the equipment of the JRC PMR IGIC RAS. Кarl Fischer titration was done using equipment of “Research Chemical and Analytical Center NRC “Kurchatov Institute” Shared Research Facilities.

Funding

This study was financially supported by the Russian Science Foundation, project no. 22-29-00791, https://rscf.ru/en/project/22-29-00791/).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry RAS, Moscow, Russia

    A. V. Polkovnichenko, N. N. Kulov, A. V. Kisel’, N. N. Kuritsyn, S. Ya. Kvashnin & E. V. Lunachev

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  1. A. V. Polkovnichenko
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  2. N. N. Kulov
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  3. A. V. Kisel’
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Correspondence to A. V. Polkovnichenko or E. V. Lunachev.

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Translated by N. Rukk

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Polkovnichenko, A.V., Kulov, N.N., Kisel’, A.V. et al. Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products. Physicochemical Foundations of Crystallization of Binary Mixtures of cis- and trans-Perfluorodecalin and Perfluorobutylcyclohexane. Theor Found Chem Eng 57, 1268–1275 (2023). https://doi.org/10.1134/S0040579523060179

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