Log in

Technology of Sintering Phosphorite with KOH

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

The paper shows a new technological approach to the processing of phosphorus-containing raw materials using Syrian phosphorite as an example. Thermodynamic calculations of possible processes of interaction of apatites with KOH and quartz are made, assumptions about the interaction are experimentally verified, and the resulting substances are determined by X-ray phase analysis. The results obtained allow us to recommend the method of sintering followed by leaching with water as a promising technology for the production of fertilizers from phosphorus-containing raw materials, bypassing the stage of production of extractive phosphoric acid.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

REFERENCES

  1. U.S. Geological Survey, 2023, Mineral commodity summaries 2023: U.S. Geological Survey, https://doi.org/10.3133/mcs2023 https://pubs.er.usgs.gov/publication/mcs2023. Cited May 27, 2023.

  2. Solovyov, A.V. and Sidorova, J.V., Phosphorus as one of the main elements in the nutrition of plant objects, Vestn. Ross. Gos. Agrar. Zaochn. Univ., 2022, no. 40, pp. 17–26.

  3. Khurramov, N., Nurmurodov, T., and Erkaev, A., Investigation of the process of obtaining extraction phosphoric acid from washed dried phosphorites, Unoversum: Tekh. Nauki, 2021, no. 2, part 3, pp. 71–76. https://doi.org/10.32743/UniTech.2021.83.2-3.71-76

  4. Mukhortova, D.D. and Zubova, N.G., Perspective methods of phosphoric acid production, Trudy IV Mezhdunarodnoi nauchno-prakticheskoi konferentsii “Sovremennye tekhnologii i avtomatizatsiya v tekhnike, upravlenii i obrazovanii” (Proc. IV Int. Nauchn.-Pract. Conf. “Modern Technologies and Automatization in Technics, Management and Education), Balakovo, 2022, vol. 2, pp. 87–89. https://biti.mephi.ru/wp-content/uploads/2022/06/%D0%A2%D0%9E%D0%9C-2.pdf. Cited May 29, 2023.

  5. Ershov, V.A. and Pimenov, S.D., Elektrotermiya fosfora (Phosphorus Electrothermy), S.-Peterb.: Khimiya, 1996.

  6. Novikova, D.A., Andreeva, A.N., Kolesnikova, T.A., and Kulikova, M.A., Ecologic-oriented method of phosphorgypsum utilization, Trudy mezdunarodnoi nauchno-prakticheskoi konferentsii “Razvitie nauki i obrazovaniya v usloviyakh mirovoi nestabil’nosti: sovremennye paradigm, problem, puti resheniya” (Proc. Int. Nauchn.-Pract. Conf. “Development of Science and Education under Conditions of the World Instability: Contemporary Paradigms, Problems, and Ways of Solving”), Rostov-on-Don, 2021, pp. 41–42.

  7. Doklady XXIX vserossiiskoi nauchno-prakticheskoi konferentsii “Sovremennye problem ekologii” (Proc. XXIX All-Russ. Nauchn.-Pract. Conf. “Contemporary Problems of Ecology”), Panarin, V.M., Ed., Tula: Innovatsionnye Tekhnol., 2022.

    Google Scholar 

  8. Turaev, D.Yu. and Pochitalkina, I.A., Theoretical and practical foundations of the selective separation of phosphate ions from phosphate ores with a high content of iron impurities with the recirculation method, Theor. Found. Chem. Eng., 2022, vol. 56, no. 2, pp. 252–264. https://doi.org/10.1134/S0040579522020142

    Article  CAS  Google Scholar 

  9. Puchkov, A.Yu., Lobaneva, E.I., and Kultygin, O.P., Algorithm for predicting the parameters of a system for processing waste apatite–nepheline ores, Prikl. Inf., 2022, vol. 17, no. 1, pp. 55–68. https://doi.org/10.37791/2687-0649-2022-17-1-55-68

    Article  Google Scholar 

  10. Puchkov, A.Yu., Sokolov, A.M., and Fedotov, V.V., Neural network analysis method of heat treatment processes of pelletized phosphate ore raw materials, Prikl. Inf., 2022, vol. 17, no. 5, pp. 62–76. https://doi.org/10.37791/2687-0649-2022-17-5-62-76

    Article  Google Scholar 

  11. Puchkov, A.Yu., Dli, M.I., Prokimnov, N.N., and Shutova, D.Yu., Multilevel algorithms for evaluating and making decisions on the optimal control of an integrated system for processing fine ore raw materials, Prikl. Inf., 2022, vol. 17, no. 6, pp. 102–121. https://doi.org/10.37791/2687-0649-2022-17-6-102-121

    Article  Google Scholar 

  12. International Centre for Diffraction Data. Powder Diffraction File JCPDS-ICDD PDF-2 (Set 1-47). (Release, 2016). www.url: https://www.icdd.com/pdf-2/. Cited May 15, 2022.

  13. Makeyev, A.V. and Kartashov, P.M., Material composition and mineralogy of phosphorites of the Al Sharqiya deposit (Syria), Trudy Fersman Nauchn. Sess. GI KNTs RAN, 2022, no. 19, pp. 206–211. https://doi.org/10.31241/FNS.2022.19.038

  14. Mamurov, B.A. and Shamshidinov, I.T., Study of the process of obtaining calcium and magnesium phosphate fertilizers by neutralizing extraction phosphoric acid with dolomite, Unoversum: Tekh. Nauki, 2022, no. 7, part 3, pp. 13–16. https://doi.org/10.32743/UniTech.2022.100.7.14014

Download references

Funding

The work was carried out in accordance with the state assignment and the plans of the Research Institute of Chemical Technology of the Ural Branch of the Russian Academy of Sciences (no. AAAA-A19-119031890028-0).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. M. Skachkov.

Ethics declarations

The author declares that he has no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Skachkov, V.M. Technology of Sintering Phosphorite with KOH. Theor Found Chem Eng 57, 316–320 (2023). https://doi.org/10.1134/S0040579523030181

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0040579523030181

Keywords:

Navigation