Abstract
Linear voltammetry in the potentiodynamic mode is used to study the electrochemical behavior of a heavy tungsten-containing VNZh alloy (in wt %: 90 W, 7 Ni, 3 Fe) and its components in ammonia–alkali electrolytes. The anodic oxidation of individual tungsten and nickel is found to be activated when NH4OH is introduced into the composition of an alkaline electrolyte. Galvanostatic electrolysis is used to perform electrochemical processing of a VNZh-type alloy with a current efficiency of about 100% for tungsten and a specific energy consumption of ~1.5 kW h/kg.
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REFERENCES
G. V. Chernyak and K. B. Povarova, Tungsten in Ammunition, Ed. by I. N. Torgun (FGUP TsNIIKhM, Moscow, 2014).
V. Kovalenko and V. Kotoc, “Selective anodic treatment of W(WC)-based superalloy scrap,” Eastern-Europ. J. Enter. Technol. 85 (1/5), 53–58 (2017).
V. V. Reznichenko, A. M. Butenko, and O. Ya. Loboiko, “Iron recovery from tungsten-containing tool alloys in the presence of ozone,” Tr. Odesskogo Politekhn. Univ., No. 2, 205–209 (2009).
G. A. Baranov, M. N. Gavrish, and D. D. Sanikovich, “Production of nanopowders in processing of the wastes of tungsten-containing alloys and investigation of their granulometric composition,” Vestn. Nats. Tekhn. Univ. Ukrainy Kiev. Politekhn. Inst., Ser. Mashinostr., No. 63, 42–46 (2011).
A. A. Palant, A. M. Levin, and L. A. Palant, “Method of electrochemical processing of the metallic wastes of tungsten–copper alloys,” RF Patent 2479652, 2013.
S. Hairunisha, G. K. Sendil, J. Prabhakar Rethinaraj, G. N. Srinivasan, P. Adaikkalam, and S. Kulandaisamy, “Studies on the preparation of pure ammonium tungstate from pure ammonium para tungstate from tungsten alloy scrap,” Hydrometallurgy 85, 67–71 (2007).
V. V. Parshutin, “Corrosion and electrochemical behavior of pseudoalloys based on tungsten and its components,” Elektron. Obrab. Mater., No. 6, 27–45 (2008).
M. D. Sakhnenko, M. V. Ved’, I. Yu. Ermolenko, and M. S. Pankrat’eva, “Electrolyte for fast selective separation of tungsten alloys,” UA Patent 50653, 2010.
R. I. Kraidenko, Yu. V. Perederin, D. S. Filatov, A. B. Manucharyants, et al., “Technology of tungsten production: state of the art of technology,” Polzunovskii Vestn. 2 (4), 135–139 (2015).
Handbook on Electrochemistry, Ed. by A. M. Sukhotin (Khimiya, Leningrad, 1981).
M. N. Dyatlov, V. Ya. Temkina, and K. I. Popov, Metal Complexones and Complexonates (Khimiya, Moscow, 1998).
A. M. Levin, O. G. Kuznetsova, and M. A. Sevost’yanov, “Electrical conductivity of NaOH–NH4OH aqueous solutions at 20°C,” in Proceedings of Conference on Scientific and Innovation World (AETERNA, Ufa, 2017), Vol. 5, pp. 31–34.
S. F. Belov, M. S. Igumnov, and A. M. Levin, “Anodic dissolution of tungsten in sodium hydroxide in the presence of \({\text{NH}}_{4}^{ + },\) \({\text{SO}}_{4}^{{2 - }},\) and \({\text{CO}}_{3}^{{2 - }}\) ions,” Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., No. 1, 124–127 (1991).
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Kuznetsova, O.G., Levin, A.M., Sevast’yanov, M.A. et al. Electrochemical Oxidation of a Heavy Tungsten-Containing VNZh-Type Alloy and Its Components in Ammonia–Alkali Electrolytes. Russ. Metall. 2019, 507–510 (2019). https://doi.org/10.1134/S0036029519050057
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DOI: https://doi.org/10.1134/S0036029519050057