SpringerLink
Log in

Some Features of the Cathodic and Anodic Nickel Depassivation during DC Polarization in Sulfuric Acid Solutions

  • Published:
Russian Metallurgy (Metally) Aims and scope

Abstract

A comparative analysis of the formation and decomposition processes and the component composition of the phases of films that passivate a nickel electrode during its dc polarization in sulfuric acid solutions with a varied value and polarity of the applied potential is performed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Physical Magnitudes: A Handbook Ed. by I. S. Grigor’ev and E. Z. Meilikhov (Energoatomizdat, Moscow, 1991).

    Google Scholar 

  2. V. A. Bryukvin, E. A. Skryleva, T. B. Elemesov, A. M. Levin, and A. O. Bol’shikh, “Mechanism of the anodic passivation of the Group VIII 3d metals in sulfuric acid solutions: I. Nickel,” Russ. Metall. (Metally), No. 11, 830–833 (2013).

  3. V. D. Yagodovskii and S. K. Rei, “Induction of metallic surface heterogeneity during adsorption,” Zh. Fiz. Khim. 63 (10), 2485–2489 (1989).

    Google Scholar 

  4. I. I. Mikhalenko and V. D. Yagodovskii, “Forms of sorbed hydrogen and their influence on the oxidation of Co from Pd and Ta,” Kinet. Katal. 43 (2), 256–263 (2004).

    Google Scholar 

  5. B. A. Kolachev, A. A. Il’in, V. A. Lavrenko, and Yu. V. Levinskii, Hydride Systems: A Handbook (Metallurgiya, Moscow, 1992).

    Google Scholar 

  6. E. A. Skryleva, V. A. Bryukvin, T. B. Elemesov, and A. M. Levin, “Passivation of nickel in sulfuric acid solutions during its polarization by direct current in the region of mixed potentials,” Russ. Metall. (Metally), No. 11, 865–868 (2014).

  7. V. A. Bryukvin, V. T. D’yachenko, E. A. Elemesov, and A. O. Bol’shikh, “Reaction behavior of nickel in sulfuric acid solutions during direct current polarization,” Tsvetn. Met., No. 8, 26–35 (2014).

  8. A. N. Podobaev and I. I. Reformatskaya, “Initial stages of nickel passivation and dissolution in acidic sulfate solutions,” Zashch. Met. 42, 73–75 (2006).

    Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was carried out on the equipment of the Center for Collective Use Materials Science and Metallurgy at the National University of Science and Technology MISiS.

The work was supported by the Ministry of Education and Science of the Russian Federation and the Russian Foundation for Basic Research, project no. 13-08-00200.

Author information

Authors and Affiliations

  1. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991, Moscow, Russia

    V. A. Bryukvin, A. M. Levin, O. G. Kuznetsova, O. I. Tsybin & A. O. Bol’shikh

  2. National University of Science and Technology MISiS, 119991, Moscow, Russia

    E. A. Skryleva

  3. OOO NPP Kvalitet, Moscow, Russia

    M. N. Naftal’

Authors
  1. V. A. Bryukvin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Skryleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. N. Naftal’
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Levin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. G. Kuznetsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. O. I. Tsybin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. O. Bol’shikh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Bryukvin.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bryukvin, V.A., Skryleva, E.A., Naftal’, M.N. et al. Some Features of the Cathodic and Anodic Nickel Depassivation during DC Polarization in Sulfuric Acid Solutions. Russ. Metall. 2019, 241–246 (2019). https://doi.org/10.1134/S0036029519030029

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036029519030029

Keywords:

Search

Navigation