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Investigation of the Pore Structure of Exfoliated Graphite Based on Highly Oriented Pyrolytic Graphite Nitrate

  • STRUCTURE OF MATTER AND QUANTUM CHEMISTRY
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Abstract

Graphite intercalated compounds (GICs) with different stage numbers were prepared from highly oriented pyrolytic graphite (HOPG) and nitric acid using a chemical method. Exfoliated graphite (EG-T) was synthesized from GICs by water treatment followed by thermal shock. The effects of the graphite oxidation depth on the EG-T thermal expansion coefficient, volatile content, and total porosity were examined. However, the main purpose of this work was investigation of the dependence of the inner EG-T pore structure on the level of oxidation. Thus, we studied the micro- and mesopore structure and specific surface area by nitrogen porosimetry and the modern 2D-NLDFT method to calculate the pore size distribution and pore volume. As well, we performed a mercury porosimetry experiment to determine the macropore characteristics. We examined the pore space using a number of scanning electron micrographs of EG-T particle cross-sections using an image processing technique. In this way we showed the strong correlation between the EG-T pore structure parameters and oxidation depth of graphite.

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ACKNOWLEDGMENTS

This research was performed according to the Development program of the Interdisciplinary Scientific and Educational School of Moscow State University “The future of the planet and global environmental change.”

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. Krautsou, O. N. Shornikova, A. I. Bulygina, A. L. Kustov & V. V. Avdeev

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. B. Solopov

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  1. A. Krautsou
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  2. O. N. Shornikova
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  3. A. I. Bulygina
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  6. V. V. Avdeev
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Correspondence to A. Krautsou.

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Krautsou, A., Shornikova, O.N., Bulygina, A.I. et al. Investigation of the Pore Structure of Exfoliated Graphite Based on Highly Oriented Pyrolytic Graphite Nitrate. Russ. J. Phys. Chem. 97, 1174–1182 (2023). https://doi.org/10.1134/S0036024423060122

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