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Evolution of the Impurity Sites and Electronic Spectra of Aluminum Phthalocyanine in a Silicate Nanoreactor

  • PHYSICAL CHEMISTRY OF NANOCLUSTERS, SUPRAMOLECULAR STRUCTURES, AND NANOMATERIALS
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Abstract

The evolution of the electronic absorption spectra of substituted aluminum phthalocyanine incorporated into a nanoporous silicate gel matrix has been studied. The decomposition of the contour of the long-wavelength Q-absorption band of molecules into Voigt components reveals the dependence of the formation of various types of impurity sites in the matrix nanopores, which act as a solid-state nanoreactor, on the drying time of the matrix. Possible mechanisms of the effect of the internal structure of the synthesized silicate material during the transition from a sol state to a dried xerogel state on the spectral properties of phthalocyanine impurity molecules are discussed. Models of the interaction of the impurity molecules with the surface of the matrix nanopores during drying are considered; the features of the evolution of the resulting impurity sites are elucidated.

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ACKNOWLEDGMENTS

The authors thank Prof. Claudine Crepin-Gilbert (Institut des Sciences Moléculaires d’Orsay, France) for providing aluminum phthalocyanine and fruitful discussion of the results.

Funding

This work was supported in part by the Belarusian Republican Foundation for Basic Research (agreement no. F21MS-017).

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Authors and Affiliations

  1. Belarusian State Agrarian Technical University, 220023, Minsk, Belarus

    S. M. Arabei, I. V. Stanishevsky & S. V. Slonskaya

  2. Stepanov Institute of Physics, National Academy of Sciences of Belarus, 220072, Minsk, Belarus

    T. A. Pavich

Authors
  1. S. M. Arabei
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  2. I. V. Stanishevsky
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  3. T. A. Pavich
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  4. S. V. Slonskaya
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Corresponding author

Correspondence to S. M. Arabei.

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Translated by M. Timoshinina

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Arabei, S.M., Stanishevsky, I.V., Pavich, T.A. et al. Evolution of the Impurity Sites and Electronic Spectra of Aluminum Phthalocyanine in a Silicate Nanoreactor. Russ. J. Phys. Chem. 97, 1195–1201 (2023). https://doi.org/10.1134/S003602442306002X

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  • DOI: https://doi.org/10.1134/S003602442306002X

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