Abstract
A study is performed of patterns of the destruction of β-substituted and β,β-annelated porphyrazines in the presence of cyclic and acyclic nitrogen-containing bases in dimethylsulfoxide. Possible schemes of the mechanism are proposed and substantiated. It is shown how the NH acidity of the porphyrazine macrocycle, the spatial structure of the nitrogen-containing base, and its proton-acceptor ability affect the kinetic parameters of destruction. Structural data of proton-transfer complexes in dimethylsulfoxide are discussed.
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This work was supported by the Ivanovo State University of Chemistry and Technology, grant no. 13-ISUCT-21.
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Petrov, O.A. Destruction of Porphyrazines in Organic Proton-Acceptor Media. Russ. J. Phys. Chem. 96, 470–477 (2022). https://doi.org/10.1134/S0036024422030207
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DOI: https://doi.org/10.1134/S0036024422030207