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Modifying Suspensions for the Electrophoretic Deposition of BaCe0.5Zr0.3Y0.1Yb0.1O3–δ Solid Electrolyte

  • COLLOIDAL CHEMISTRY AND ELECTROCHEMISTRY
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Abstract

Powder of proton-conducting BaCe0.5Zr0.3Y0.1Yb0.1O3−δ (BCZYYbO) electrolyte is synthesized using the citrate–nitrate technique. The dispersity of the BCZYYbO suspension in a mixed medium (isopropanol/acetylacetone 70/30 vol %) is investigated. The effects of ultrasonic treatment and centrifuging on the size distribution of aggregates and the effective hydrodynamic diameter are determined. The suspension is characterized by a bimodal size distribution of aggregates. The zeta potential values are determined for the initial BCZYYbO suspension (+7 mV), a suspension with the addition of molecular iodine (0.4 g/L) (+7 mV), and suspensions of the modified initial powder (1 wt % of copper oxide BCZYYbO_CuO) (+11 mV) of the same concentration (15 g/L). It is found that adding iodine does not affect the value of the zeta potential; however it does affects the pH of the suspension. In contrast to the modified suspensions, it is impossible to conduct EPD from the initial BCZYYbO suspension. A refinement is proposed to transform the EPD mechanism from a nonaqueous suspension with the participation of iodine and the trace water content associated with the change in the concentration of H+ and I– ions adsorbed on the particles in the BCZYYbO suspension.

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REFERENCES

  1. S. Hossain, A. M. Abdalla, S. N. B. Jamain, et al., Renewable Sustainable Energy Rev. 79, 750 (2017). https://doi.org/10.1016/j.rser.2017.05.147

    Article  CAS  Google Scholar 

  2. A. Tarancón, Energies 2, 1130 (2009). https://doi.org/10.3390/en20401130

    Article  CAS  Google Scholar 

  3. E. Pikalova and E. Kalinina, J. Energy Prod. Mgm. 4, 1 (2019). https://doi.org/10.2495/EQ-V4-N1-1-27

    Article  Google Scholar 

  4. D. A. Medvedev and S. Ricote, J. Solid State Electrochem. 24, 1445 (2020). https://doi.org/10.1007/s10008-020-04655-6

    Article  CAS  Google Scholar 

  5. J. Lyagaeva, B. Antonov, L. Dunyushkina, et al., Electrochim. Acta 192, 80 (2016). https://doi.org/10.1016/j.electacta.2016.01.144

    Article  CAS  Google Scholar 

  6. J. Lyagaeva, G. Vdovin, L. Hakimova, et al., Electrochim. Acta 23, 554 (2017). https://doi.org/10.1016/j.electacta.2017.08.149

    Article  CAS  Google Scholar 

  7. Y. Zhang, D. **e, B. Chi, et al., Asia Pacif. J. Chem. Eng. 14, e2322 (2019). https://doi.org/10.1002/apj.2322

    Article  CAS  Google Scholar 

  8. D. Medvedev, J. Lyagaeva, S. Plaksin, et al., J. Power Sources 273, 716 (2015). https://doi.org/10.1016/j.jpowsour.2014.09.116

    Article  CAS  Google Scholar 

  9. L. Yang, S. Wang, K. Blinn, et al., Science (Washington, DC, U. S.) 326, 126 (2009). https://doi.org/10.1126/science.1174811

    Article  CAS  Google Scholar 

  10. B. Shri Prakash, R. Pavitra, S. Senthil Kumar, et al., J. Power Sources 381, 136 (2018). https://doi.org/10.1016/j.jpowsour.2018.02.003

    Article  CAS  Google Scholar 

  11. E. Yu. Pikalova and E. G. Kalinina, Russ. Chem. Rev. 90, 703 (2021). https://doi.org/10.1070/RCR4966

  12. M. Ananyev, D. Medvedev, A. Gavrilyuk, et al., Electrochim. Acta 125, 371 (2014). https://doi.org/10.1016/j.electacta.2013.12.161

    Article  CAS  Google Scholar 

  13. D. Gao and R. Guo, J. Alloys Compd. 493, 288 (2010). https://doi.org/10.1016/j.jallcom.2009.12.082

    Article  CAS  Google Scholar 

  14. A. Afif, N. Radenahmad, J. Zaini, et al., Process. Appl. Ceram. 12, 180 (2018). https://doi.org/10.2298/PAC1802180A

    Article  CAS  Google Scholar 

  15. B. Wang, L. Bi, and X. S. Zhao, J. Power Sources 399, 207 (2018). https://doi.org/10.1016/j.jpowsour.2018.07.087

    Article  CAS  Google Scholar 

  16. Y. G. Lyagaeva, D. A. Medvedev, A. K. Demin, T. V. Yaroslavtseva, S. V. Plaksin, and N. M. Porotnikova, Semiconductors 48, 1353 (2014). https://doi.org/10.1134/S1063782614100182

    Article  CAS  Google Scholar 

  17. H. Dai, H. Kou, H. Wang, and L. Bi, Electrochem. Commun. 96, 11 (2018). https://doi.org/10.1016/j.elecom.2018.09.001

    Article  CAS  Google Scholar 

  18. E. Yu. Pikalova and E. G. Kalinina, Renewable Sustainable Energy Rev. 116, 109440 (2019). https://doi.org/10.1016/j.rser.2019.109440

    Article  CAS  Google Scholar 

  19. E. G. Kalinina and E. Yu. Pikalova, Russ. Chem. Rev. 88, 1179 (2019). https://doi.org/10.1070/RCR4889

    Article  CAS  Google Scholar 

  20. C. Argirusis, J. Grosse-Brauckmann, G. Sourkouni, et al., Key Eng. Mater. 412, 125 (2009). https://doi.org/10.4028/www.scientific.net/KEM.412.125

    Article  CAS  Google Scholar 

  21. E. D. Bartolomeo, M. Zunic, L. Chevallier, et al., J. Electrochem. Soc. 25, 577 (2009). https://doi.org/10.1149/1.3205569

    Article  Google Scholar 

  22. Y. Itagaki, Y. Yamamoto, H. Aono, et al., J. Ceram. Soc. Jpn. 125, 528 (2017). https://doi.org/10.2109/jcersj2.17048

    Article  CAS  Google Scholar 

  23. F. Chen and M. Liu, J. Eur. Ceram. Soc. 21, 127 (2001). https://doi.org/10.1016/S0955-2219(00)00195-3

    Article  CAS  Google Scholar 

  24. T. Ishihara, K. Sato, and Y. Takita, J. Am. Ceram. Soc. 79, 913 (1996). https://doi.org/10.1111/j.1151-2916.1996.tb08525.x

    Article  CAS  Google Scholar 

  25. C. Kleinlogel and L. J. Gauckler, Solid State Ionics 135, 567 (2000). https://doi.org/10.1016/S0167-2738(00)00437-9

    Article  CAS  Google Scholar 

  26. E. Kalinina, A. Kolchugin, K. Shubin, et al., Appl. Sci. 10, 6535 (2020). https://doi.org/10.3390/app10186535

    Article  CAS  Google Scholar 

  27. D. De and P. S. Nicholson, J. Am. Ceram. Soc. 82, 3031 (1999). https://doi.org/10.1111/j.1151-2916.1999.tb02198.x

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The authors thank Prof. A.P. Safronov for his help with our DLS measurements.

The study was carried out on the equipment of the Shared Access Center of the IEP UB RAS.

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 20-03-00151. Investigation of the kinetic properties of the suspensions was performed within the framework of the state assignment of IEP UB RAS (EPD thin-layer coatings, no. АААА-А19-119061090040-7).

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Authors and Affiliations

  1. Institute of Electrophysics, Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    E. G. Kalinina

  2. Ural Federal University, 620002, Yekaterinburg, Russia

    E. G. Kalinina & E. Yu. Pikalova

  3. Institute of High Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    E. Yu. Pikalova

Authors
  1. E. G. Kalinina
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  2. E. Yu. Pikalova
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Correspondence to E. G. Kalinina.

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Translated by D. Kharitonov

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Kalinina, E.G., Pikalova, E.Y. Modifying Suspensions for the Electrophoretic Deposition of BaCe0.5Zr0.3Y0.1Yb0.1O3–δ Solid Electrolyte. Russ. J. Phys. Chem. 95, 1942–1947 (2021). https://doi.org/10.1134/S0036024421090077

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