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Gas Chromatographic Study of a Composite Sorbent Based on Metal-Organic Framework MIL-53(Al)

  • PHYSICAL CHEMISTRY OF SEPARATION PROCESSES: CHROMATOGRAPHY
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Abstract

The retention regularities and the thermodynamic characteristics of the sorption of volatile organic compounds from the gas phase were studied for the chromatography columns packed with composite sorbents based on the MIL-53(Al) metal-organic framework and polydiphenyldimethylsiloxane (PPMS). It was shown that with an increase in the content of MIL-53(Al) in the binary sorbent to 73 wt %, retention is predominantly associated with adsorption in the microporous structure of MIL-53(Al) rather than dissolution in the PFMS film. It has been shown that the adsorbate–adsorbent interaction in the orthorhombic channels of MIL-53(Al) depends to a greater extent on the dispersion attractive forces than the dipole–dipole and specific interactions.

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ACKNOWLEDGMENTS

The authors are grateful to Leading Researcher of the Laboratory of Physical and Chemical Foundations of Chromatography and Gas Chromatography–Mass Spectrometry, B.R. Saifutdinov, Ph.D., from Frumkin Institute of Physical Chemistry and Electrochemistry for the provided samples of the MOCP MIL-53(Al) and to the director of Samara Center for Theoretical Materials Science, Prof. V.A. Blatov, Doctor of Science in Chemistry, for advice and technical assistance.

Funding

The study was carried out with the financial support of the Russian Foundation for Basic Research, project no. 18-29-04010 MK.

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Authors and Affiliations

  1. Samara National Research University, Samara, Russia

    M. Yu. Pariichuk, K. A. Kopytin, L. A. Onuchak & Yu. V. Martina

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  1. M. Yu. Pariichuk
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  2. K. A. Kopytin
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  3. L. A. Onuchak
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  4. Yu. V. Martina
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Corresponding author

Correspondence to L. A. Onuchak.

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Translated by M. Drozdova

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Pariichuk, M.Y., Kopytin, K.A., Onuchak, L.A. et al. Gas Chromatographic Study of a Composite Sorbent Based on Metal-Organic Framework MIL-53(Al). Russ. J. Phys. Chem. 95, 806–811 (2021). https://doi.org/10.1134/S0036024421040208

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