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The role of radical and molecular reactions in the processes of ozonization of aqueous solutions of non-dissociating compounds

  • Chemical Kinetics and Catalysis
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Abstract

A theoretical approach to determining regions where ozonation proceeds by radical and molecular mechanisms is proposed. Ozonation of aqueous solutions of non-dissociating substances in open and closed reactors is considered. The effect of the values of the rate constants of reactions between the substrate and ozone, OH radicals, and O− ions, as well as that of the conditions of ozonation (pH of the solution, concentration of the reagents, and so on) on the role of radical and molecular reactions in the ozonation of chemical compounds is analyzed.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119992, Russia

    A. N. Ignat’ev, A. N. Pryakhin & V. V. Lunin

Authors
  1. A. N. Ignat’ev
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  2. A. N. Pryakhin
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  3. V. V. Lunin
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Correspondence to A. N. Ignat’ev.

Additional information

Original Russian Text © A.N. Ignat’ev, A.N. Pryakhin, V.V. Lunin, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 4, pp. 661–667.

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Ignat’ev, A.N., Pryakhin, A.N. & Lunin, V.V. The role of radical and molecular reactions in the processes of ozonization of aqueous solutions of non-dissociating compounds. Russ. J. Phys. Chem. 84, 578–583 (2010). https://doi.org/10.1134/S0036024410040102

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  • DOI: https://doi.org/10.1134/S0036024410040102

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