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Influence of flow parameters of the mobile phase on the retention and thermodynamic characteristics of sorption in gas-liquid chromatography

  • Physical Chemistry of Separation Processes. Chromatography
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Abstract

The influence of the flow parameters of the mobile phase (flow rate and mean pressure in the column) on the retention and thermodynamic characteristics of sorption in gas-liquid chromatography is studied experimentally. Conditions are formulated under which the chromatographic process can be described in terms of the theory of equilibrium gas-liquid chromatography with an ideal gas as the mobile phase and the distribution of the sorbate between phases is not affected by the presence of a weakly sorbed carrier gas.

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Authors and Affiliations

  1. Samara State University, Samara, Russia

    L. A. Onuchak, S. Yu. Kudryashov & Yu. I. Arutyunov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    V. A. Davankov

Authors
  1. L. A. Onuchak
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  2. S. Yu. Kudryashov
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  3. Yu. I. Arutyunov
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  4. V. A. Davankov
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Additional information

Original Russian Text © L.A. Onuchak, S. Yu. Kudryashov, Yu.I. Arutyunov, V.A. Davankov, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 8, pp. 1493–1498.

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Onuchak, L.A., Kudryashov, S.Y., Arutyunov, Y.I. et al. Influence of flow parameters of the mobile phase on the retention and thermodynamic characteristics of sorption in gas-liquid chromatography. Russ. J. Phys. Chem. 80, 1315–1320 (2006). https://doi.org/10.1134/S0036024406080267

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  • DOI: https://doi.org/10.1134/S0036024406080267

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