Abstract
The thermodynamic characteristics of adsorption of several organic compounds on the carbon adsorbent Carbopack B before and after its modification by a monomolecular layer of cholesteryl-n-pentyl oxybenzoate were determined by gas chromatography. The initial adsorbent was close in its properties to graphitized carbon black. Modification weakened adsorbate-adsorbent attraction and increased the mobility of adsorbed molecules, to a greater extent for nonpolar adsorbents and to a lesser extent for compounds capable of specifically interacting with modifier molecules.
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References
A. V. Kiselev and Ya. I. Yashin, Gas Adsorption Chromatography (Nauka, Moscow, 1967) [in Russian].
N. N. Avgul’, A. V. Kiselev, and D. P. Poshkus, Adsorption of Gases and Vapors on Homogeneous Surfaces (Khimiya, Moscow, 1975) [in Russian].
A. V. Kiselev, D. P. Poshkus, and Ya. I. Yashin, Molecular Fundamentals of Adsorption Chromatography (Khimiya, Moscow, 1986) [in Russian].
Sigma-Aldrich Co., Supelco Bulletins Nos. 722P, 737F, 743L, 775E, 790C, 816B, 824C, 856B.
V. I. Nazarova, K. D. Shcherbakova, and O. A. Shcherbakova, J. Chromatogr. 600, 59 (1992).
V. I. Nazarova, K. D. Shcherbakova, and O. A. Shcherbakova, Zh. Fiz. Khim. 67(10), 2041 (1993).
V. I. Nazarova and K. D. Shcherbakova, Zh. Fiz. Khim. 67(11), 2063 (1997) [Russ. J. Phys. Chem. 67 (11), 1866 (1997)].
L. A. Onuchak, S. V. Lapshin, S. Yu. Kudryashov, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 46(4), 62 (2003).
L. A. Onuchak and S. V. Lapshin, Vestn. Sam. Gos. Univ., Special issue, p. 137 (2002).
S. V. Lapshin, S. Yu. Kudryashov, L. A. Onuchak, and Yu. G. Stupnikova, Vestn. Sam. Gos. Univ., Second Special Issue, p. 135 (2003).
L. A. Onuchak, S. V. Lapshin, S. Yu. Kudryashov, and O. B. Akopova, Zh. Fiz. Khim. 75(5), 943 (2005) [Russ. J. Phys. Chem. 75 (5), 817 (2005)].
P. A. Elkington and G. Curthoys, J. Phys. Chem. 73, 2321 (1969).
L. D. Belyakova, A. V. Kiselev, and N. V. Kovaleva, Zh. Fiz. Khim. 40(7), 1494 (1966).
A. V. Kiselev, I. A. Migunova, and Ya. I. Yashin, Zh. Fiz. Khim. 42(5), 1235 (1968).
A. V. Kiselev, G. M. Petov, and K. D. Shcherbakova, Zh. Fiz. Khim. 41(6), 1419 (1967).
E. V. Kalashnikova, A. V. Kiselev, R. S. Petrova, K. D. Shcherbakova, and D. P. Poshkus, Chromatografia 12(12), 799 (1976).
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Original Russian Text © S.Yu. Kudryashov, Yu.G. Kuraeva, L.A. Onuchak, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 7, pp. 1268–1271.
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Kudryashov, S.Y., Kuraeva, Y.G. & Onuchak, L.A. The adsorption of organic compounds on a modified carbon adsorbent Carbopack B. Russ. J. Phys. Chem. 80, 1115–1118 (2006). https://doi.org/10.1134/S003602440607020X
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DOI: https://doi.org/10.1134/S003602440607020X