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Substituted Phthalimides Linked to the Cymantrenyl Moiety: Molecules with Tunable Optical and Electrochemical Properties

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Abstract—

The results of investigation of the optical and electrochemical properties of substituted phthalimides linked to a cymantrenyl moiety by IR and NMR spectroscopy, UV-Vis spectroscopy, and cyclic voltammetry and also by DFT calculations are presented. It was shown that the optical, donor-acceptor, and redox properties of the organometallic phthalimides are affected by substituents in position 1 of the side chain of the cymantrene Cp and in position 4 of the phthalimide benzene ring. The reactions of dicarbonyl chelates with external ligands in the dark attest to hemilability of the Mn–O=C(imide) bond.

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ACKNOWLEDGMENTS

Infrared and NMR spectral studies were carried out using the research equipment of the Center of Molecular Structure Investigation of the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, supported by the Ministry of Science and Higher Education of the Russian Federation.

Funding

This study was supported by the Russian Science Foundation (RSF no. 23-23-00192).

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334, Moscow, Russia

    E. S. Kelbysheva, T. V. Strelkova, M. G. Ezernitskaya & L. N. Telegina

  2. Faculty of Chemistry and Technology, Tver State University, 170100, Tver, Russia

    V. G. Alekseev

Authors
  1. E. S. Kelbysheva
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  2. T. V. Strelkova
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  3. M. G. Ezernitskaya
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  4. V. G. Alekseev
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  5. L. N. Telegina
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Corresponding author

Correspondence to E. S. Kelbysheva.

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Additional information

Translated by Z. Svitanko

Supplementary Information

The supplementary information presents experimental data and characterization of the obtained compounds by NMR (Fig. S1–S11), IR (Fig. S12–S16), and CV (Fig. S17–S18) and the results of DFT calculations (Fig. S19–S33, Table S1).

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Kelbysheva, E.S., Strelkova, T.V., Ezernitskaya, M.G. et al. Substituted Phthalimides Linked to the Cymantrenyl Moiety: Molecules with Tunable Optical and Electrochemical Properties. Russ. J. Inorg. Chem. 68, 1237–1246 (2023). https://doi.org/10.1134/S0036023623601435

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