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Effect of Supersonic Nitrogen Flow on Ceramic Material Ta4HfC5–SiC

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Abstract―

The behavior of the ceramic material Ta4HfC5-30 vol % SiC has been studied under the effect of supersonic flow of dissociated nitrogen, which is necessary to assess the potential application of these materials in oxygen-free gas environments at temperatures >1800°C. It has been found that as a result of heating the surface to ~2020°C in a few minutes there is a decrease to ~1915°C followed by a slow decrease to 188°C. This is probably due to the chemical processes occurring on the surface and the formation of an extremely rough microstructure. The ablation rate has been determined; it has been shown that neither at introduction of the sample into a high enthalpy nitrogen flow nor at sharp cooling (temperature drop to ~880°C in 9–10 s) cracking of the sample or detachment of the near-surface region has been observed. X-ray powder diffraction and Raman spectroscopy data allow us to conclude the complete removal of silicon carbide from the surface layer and the transformation of complex tantalum-hafnium carbide into the nitride.

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Funding

The study was supported by the Russian Foundation for Basic Research (grant no. 20-03-00502). The experiment at the VGU-4 HF plasma torch was partly supported by the State Assignment of the Ishlinsky Institute for Problems in Mechanics, Russian Academy of Sciences (grant no. AAAA-A20-120011690135-5, modification of plasmatron measuring systems). The study of the microstructure and phase composition of the samples was carried out using the equipment of the Center for Collective Use of the Physical Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, which operates with the support of the State Assignment of the Kurnakov Institute RAS in the field of fundamental scientific research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. P. Simonenko, N. P. Simonenko, I. A. Nagornov, A. S. Mokrushin & N. T. Kuznetsov

  2. Ishlinskii Institute of Problems of Mechanics, Russian Academy of Sciences, 119526, Moscow, Russia

    A. F. Kolesnikov & A. V. Chaplygin

  3. Far Eastern Federal University, 690922, Vladivostok, Russia

    E. K. Papynov, O. O. Shichalin & A. A. Belov

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  1. E. P. Simonenko
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Simonenko, E.P., Simonenko, N.P., Kolesnikov, A.F. et al. Effect of Supersonic Nitrogen Flow on Ceramic Material Ta4HfC5–SiC. Russ. J. Inorg. Chem. 68, 479–486 (2023). https://doi.org/10.1134/S0036023623600272

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