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A New Method for the Synthesis of Layered Europium Hydroxide Using Propylene Oxide as the Precipitating Agent

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Abstract

A new method for the synthesis of layered europium basic chloride in up to 90% yield was developed. The method is based on hydrolysis of europium chloride in the presence of propylene oxide. The effect of reaction temperature on the yield and composition of the products of europium chloride hydrolysis in the presence of propylene oxide was analyzed. The obtained layered europium basic chloride had pronounced anion exchange properties. The possibility of intercalation of the isonicotinate anion into a layered rare earth hydroxide was demonstrated for the first time. The intercalation of the benzoate or isonicotinate anions into layered europium hydroxide led to luminescence sensitization and decrease in the Eu3+ local symmetry.

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Funding

This study was supported by the scholarship for young scientists of President of the Russian Federation (SP-3504.2022.4) and was performed using the research equipment of the Center for Collective Use of Physical Investigation Techniques of Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. D. Sheichenko, A. D. Yapryntsev, A. A. Rodina, A. E. Baranchikov & V. K. Ivanov

  2. National Research University Higher School of Economics, 101000, Moscow, Russia

    E. D. Sheichenko

  3. Moscow State University, 119991, Moscow, Russia

    V. K. Ivanov

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  1. E. D. Sheichenko
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  2. A. D. Yapryntsev
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Correspondence to A. E. Baranchikov.

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Translated by Z. Svitanko

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Sheichenko, E.D., Yapryntsev, A.D., Rodina, A.A. et al. A New Method for the Synthesis of Layered Europium Hydroxide Using Propylene Oxide as the Precipitating Agent. Russ. J. Inorg. Chem. 68, 42–49 (2023). https://doi.org/10.1134/S0036023622602082

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