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Effect of 2 vol % Graphene Additive on Heat Transfer of Ceramic Material in Underexpanded Jets of Dissociated Air

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

Using a high-frequency induction plasma torch, features of the behavior of ultra-high-temperature ceramic materials HfB2–30 vol % SiC and (HfB2–30 vol % SiC)–2 vol % CG under the influence of underexpanded jets of dissociated air have been studied. The heat fluxes measured at the final stage of the experiment have been found to be equal to 120 and 111 W cm–2, respectively. It has been found that for graphene-modified ceramics, the surface temperature is slightly lower (by 35–75°C) compared to base UHTCs; however, the microstructure, elemental and phase composition of the oxidized surface differed greatly: for (HfB2–30 vol % SiC)–2 vol % CG, in addition to a decrease in the number of spherical convex particles formed at the exit of the borosilicate melt on the surface, the formation of openwork layered formations, presumably, boric acid, has been noted. For the estimated integral radiation coefficients, a tendency to decrease in the course of thermochemical exposure has been noted. It has been established that under the conditions of a supersonic air plasma jet flow, the studied materials manifest themselves as low-catalytic ones.

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ACKNOWLEDGMENTS

The microstructure and phase composition of the samples were studied using the equipment at the Center for Collective Use of the Physical Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, which operates with the financial support of the Ministry of Education and Science of the Russian Federation within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry.

Funding

The study of the thermochemical behavior of a sample doped with graphene was supported by the Russian Foundation for Basic Research (grant no. 20-01-00056). The experiment at the VGU-4 HF plasma torch was partly supported by the State Assignment of the Ishlinsky Institute for Problems in Mechanics, Russian Academy of Sciences (registration no. AAAA-A20-120011690135-5), and numerical modeling was partly supported by the State Assignment of the Institute of Mechanics, Moscow State University (State registration no. AAAA-A16-116021110205-0).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. P. Simonenko, N. P. Simonenko, I. A. Nagornov & N. T. Kuznetsov

  2. Ishlinsky Institute for Problems in Mechanics, Russian Academy of Sciences, 119526, Moscow, Russia

    A. F. Kolesnikov & A. V. Chaplygin

  3. Institute of Mechanics, Moscow State University, 119192, Moscow, Russia

    V. I. Sakharov

  4. Baykov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

    A. S. Lysenkov

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Simonenko, E.P., Simonenko, N.P., Kolesnikov, A.F. et al. Effect of 2 vol % Graphene Additive on Heat Transfer of Ceramic Material in Underexpanded Jets of Dissociated Air. Russ. J. Inorg. Chem. 67, 2050–2061 (2022). https://doi.org/10.1134/S0036023622601866

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