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Synthesis of Nanoscale Co3O4 Spinel and Its Application to Form Miniature Planar Structures by Microplotter Printing

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Abstract

The formation of nanocrystalline Co3O4 by chemical precipitation has been studied. The validation of the obtained semiproduct has been carried out using simultaneous thermal analysis, infrared spectroscopy, and X-ray powder diffraction analysis. The process of thermal decomposition of the semiproduct with the formation of the target oxide, which is a highly dispersed powder (the average CSR size was about 17 ± 2 nm), free of impurities has been investigated. An approach to microplotter printing of miniature planar Co3O4 nanostructures of different geometries on the surface of silicon substrates with the use of functional inks made on the basis of the obtained nanopowder has been proposed. The features of the morphology of the formed thin-film structures have been investigated. It is shown that there is practically no “coffee ring” effect. As part of the local electrophysical characteristics study of the obtained samples, the distribution maps of surface potential and capacitance contrast have been built, and the value of the electronic work function has been calculated. As a result of the study, the possibility of using the developed technology for the manufacturing of electrode structures Co3O4 for supercapacitors of planar type has been shown.

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Funding

This work was supported by the Council on grants of the President of the Russian Federation for state support of young Russian scientists MK-1749.2022.1.3 (in terms of obtaining oxide nanopowder and coating formation). X-ray powder diffraction and SEM studies were carried out using shared experimental facilities supported by the Ministry of Science and Higher Education of the Russian Federation as part of the IGIC RAS state assignment.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    T. L. Simonenko, N. P. Simonenko, Ph. Yu. Gorobtsov, E. P. Simonenko & N. T. Kuznetsov

  2. National Research University Higher School of Economics, 109028, Moscow, Russia

    Ya. P. Topalova

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  1. T. L. Simonenko
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Correspondence to T. L. Simonenko.

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Simonenko, T.L., Simonenko, N.P., Topalova, Y.P. et al. Synthesis of Nanoscale Co3O4 Spinel and Its Application to Form Miniature Planar Structures by Microplotter Printing. Russ. J. Inorg. Chem. 67, 1939–1947 (2022). https://doi.org/10.1134/S003602362260174X

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