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Synthesis of Vanadium-Doped Nano-Sized WO3 by a Combination of Sol–Gel Process and Hydrothermal Treatment

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Abstract

The synthesis of nano-sized oxide WO3–25 at % VO2 by a combination of sol–gel process and hydrothermal treatment using metal alkoxoacetylacetonates as precursors was studied. The synthesis gave the oxide powder isomorphous to hexagonal tungsten(VI) oxide. The thermal behavior of the powder in an air flow was studied by simultaneous thermal analysis in the temperature range of 25–600°C. The resulting particles were shaped as nanorods. Using Kelvin probe force microscopy, the electron work function of the material surface was determined.

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Funding

This study was partly supported by the Russian Foundation for Basic Research (project no. 20-33-90136, synthesis of nano-sized WO3–25 at. % VO2) and by the Ministry of Education and Science of the Russian Federation within the framework of the state assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences (study of the local electrophysical properties of the material). Powder X-ray diffraction study and SEM examination were carried out using equipment of the Center for Collective Use of the Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    F. Yu. Gorobtsov, M. K. Grigoryeva, T. L. Simonenko, N. P. Simonenko, E. P. Simonenko & N. T. Kuznetsov

  2. National Research University “Higher School of Economics”, 101000, Moscow, Russia

    M. K. Grigoryeva

Authors
  1. F. Yu. Gorobtsov
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  2. M. K. Grigoryeva
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  3. T. L. Simonenko
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  4. N. P. Simonenko
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  5. E. P. Simonenko
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  6. N. T. Kuznetsov
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Correspondence to F. Yu. Gorobtsov.

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Translated by Z. Svitanko

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Gorobtsov, F.Y., Grigoryeva, M.K., Simonenko, T.L. et al. Synthesis of Vanadium-Doped Nano-Sized WO3 by a Combination of Sol–Gel Process and Hydrothermal Treatment. Russ. J. Inorg. Chem. 67, 1706–1710 (2022). https://doi.org/10.1134/S0036023622601131

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  • DOI: https://doi.org/10.1134/S0036023622601131

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