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Smart Sensing Supramolecular Coordination Polymer Based on New Viologen Ligand Exhibiting Multiple Solid Detection and Inducing Apoptosis Properties

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Abstract

Through the self-assembly of 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine]-1,1'-diium (H2bcbpy·2Cl) and pyromellitic acid (H4BTC), a novel multifunctional and multichromic organic supramolecular coordination polymer named, [(BTC) (bcbpy)]·2H2O (1), has been successfully synthesized. Complex 1 shows the photochromic behavior by electron-transfer (ET) progress within 1s, because of the viologen radical formation. Besides, 1 can detect five different kinds of organic amines and can display different color changes, but the structure of 1 was destroyed. In addition, the ability of 1 to induce apoptosis of cervical cancer cells was studied in this work.

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Funding

This work was supported by National Natural Science Foundation of China (3A5205754428) and Jilin Provincial Department of Science and Technology (20190201241JC).

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Authors and Affiliations

  1. Department of Obstetrics and Gynecology, the First Hospital of Jilin University, 130000, Changchun, China

    W. Dong, C. F. **u, C. Y. Liu, W. N. Wu, L. Z. Huang & H. P. Zhang

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, 130000, Changchun, China

    H. Y. Wang

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  1. W. Dong
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  2. C. F. **u
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  3. C. Y. Liu
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  4. W. N. Wu
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  7. H. P. Zhang
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Correspondence to H. P. Zhang.

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Dong, W., **u, C.F., Liu, C.Y. et al. Smart Sensing Supramolecular Coordination Polymer Based on New Viologen Ligand Exhibiting Multiple Solid Detection and Inducing Apoptosis Properties. Russ. J. Inorg. Chem. 67, 1973–1978 (2022). https://doi.org/10.1134/S0036023622100618

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