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Formation of Strontium Hexaaluminate in Alumina–Tetragonal Zirconia Systems Modified with Strontium Cations

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Abstract

The effect of modifying strontium cations on the phase composition of the sol–gel synthesized matrix systems containing 20% of Al2O3 and 80% of a tetragonal zirconia polycrystals (TZP) solid solution stabilized by cerium [Ce-TZP] and ytterbium [Yb-TZP] cations is studied. The microstructure of the composites with a [Yb-TZP] matrix has a more fine-grained composition (200–500 nm) than the microstructure of the [Ce-TZP] matrix composites, whose grain sizes range within 800–1500 nm. Independently of the matrix solid solution type, modification promotes the formation of composites with a three-grain microstructure including long prismatic SrAl12O19 grains, which may perform dispersion strengthening in the composites.

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Funding

This work was performed within the framework of State Assignment no. 075-00746-19-00.

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Authors and Affiliations

  1. Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, 119334, Moscow, Russia

    A. A. Il’icheva, L. I. Podzorova, V. P. Sirotinkin, O. S. Antonova, A. A. Konovalov, V. E. Kutuzova & O. I. Pen’kova

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  1. A. A. Il’icheva
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  2. L. I. Podzorova
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  3. V. P. Sirotinkin
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  4. O. S. Antonova
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  5. A. A. Konovalov
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  6. V. E. Kutuzova
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  7. O. I. Pen’kova
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Correspondence to L. I. Podzorova.

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Translated by E. Glushachenkova

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Il’icheva, A.A., Podzorova, L.I., Sirotinkin, V.P. et al. Formation of Strontium Hexaaluminate in Alumina–Tetragonal Zirconia Systems Modified with Strontium Cations. Russ. J. Inorg. Chem. 65, 154–160 (2020). https://doi.org/10.1134/S0036023620020060

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  • DOI: https://doi.org/10.1134/S0036023620020060

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