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Thermal properties and ion mobility in complex antimony(III) fluorides with α-amino acids

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Abstract

Differential thermal analysis (DTA) and (19F, 1H) NMR spectroscopy were used to study thermal properties and ion mobility in complex antimony(III) fluorides with amino acids of composition [(CH3)2CH(CH2)CH(NH3)COOH]SbF4 (LeuHSbF4), SbF3[(CH3)2CH(CH2)CH(+NH3)COO−] (SbF3 · Leu), and SbF3[(CH3)2CHCH(+NH3)COO−] (SbF3 · Val). Ionic conductivity in L-leucinium tetrafluoroantimonate(III) was studied using impedance spectroscopy. LeuHSbF4 was found to undergo a diffusion phase transition to a relatively highly conductive state in the range 385–415 K with an attendant loss of thermal stability (softening) of the high-temperature phase.

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Authors and Affiliations

  1. Institute of Chemistry, Far-East Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. Ya. Kavun, N. A. Didenko, N. V. Makarenko, A. B. Slobodyuk, E. B. Merkulov & L. A. Zemnukhova

  2. Institute of Solid-State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, ul. Kutateladze 18, Novosibirsk, 630128, Russia

    N. F. Uvarov

Authors
  1. V. Ya. Kavun
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  2. N. A. Didenko
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  3. N. V. Makarenko
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  4. A. B. Slobodyuk
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  5. E. B. Merkulov
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  6. N. F. Uvarov
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  7. L. A. Zemnukhova
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Additional information

Original Russian Text © V.Ya. Kavun, N.A. Didenko, N.V. Makarenko, A.B. Slobodyuk, E.B. Merkulov, N.F. Uvarov, L.A. Zemnukhova, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 9, pp. 1344–1349.

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Kavun, V.Y., Didenko, N.A., Makarenko, N.V. et al. Thermal properties and ion mobility in complex antimony(III) fluorides with α-amino acids. Russ. J. Inorg. Chem. 57, 1262–1266 (2012). https://doi.org/10.1134/S0036023612090100

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  • DOI: https://doi.org/10.1134/S0036023612090100

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